Efficient diastereoselective intermolecular rhodium-catalyzed C-H amination

被引：218

作者：

Liang, Chungen

Robert-Pedlard, Fabien

Fruit, Corinne

Mueller, Paul

Dodd, Robert H.

Dauban, Philippe

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

[2] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 28期

关键词：

amination; C-H insertion; hypervalent iodine; nitrenes; rhodium;

D O I：

10.1002/anie.200601248

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Successful matchmaking: The combination of a chiral nitrene precursor with a chiral rhodium(II) catalyst is the key factor that allows efficient intermolecular regioselective C-H amination. Good-to-excellent yields and excellent diastereoselectivities can be obtained with a stoichiometric amount of the C-H bond containing substrate. nttl = N-1,8-naphthoyl-tert-leucine. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4641 / 4644

页数：4

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