Improvement in electrical, thermal and mechanical properties of epoxy by filling carbon nanotube

被引:159
|
作者
Zhou, Y. X. [1 ]
Wu, P. X. [2 ]
Cheng, Z-Y. [2 ]
Ingram, J. [1 ]
Jeelani, S. [1 ]
机构
[1] Tuskegee Univ, Ctr Adv Mat, Tuskegee, AL 36088 USA
[2] Auburn Univ, Mat Res & Educ Ctr, Auburn, AL 36849 USA
来源
EXPRESS POLYMER LETTERS | 2008年 / 2卷 / 01期
关键词
nanocomposites; carbon nanotubes; epoxy resin; electric-thermal-mechanical properties;
D O I
10.3144/expresspolymlett.2008.6
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, electrical, thermal and mechanical properties of multi-walled carbon nanotubes (CNTs) reinforced Epon 862 epoxy have been evaluated. Firstly, 0.1, 0.2, 0.3, and 0.4 wt% CNT were infused into epoxy through a high intensity ultrasonic liquid processor and then mixed with EpiCure curing agent W using a high speed mechanical agitator. Electric conductivity, dynamic mechanical analysis (DMA), three point bending tests and fracture tests were then performed on unfilled, CNT-filled epoxy to identify the loading effect on the properties of materials. Experimental results show significant improvement in electric conductivity. The resistivity of epoxy decreased from 10(14) Omega.m of neat epoxy to 10 Omega.m with 0.4% CNT. The experimental results also indicate that the frequency dependent behavior of CNT/epoxy nanocomposite can be modeled by R-C circuit, permittivity of material increase with increasing of CNT content. DMA studies revealed that filling the carbon nanotube into epoxy can produce a 90% enhancement in storage modulus and a 17 degrees C increase in T(g). Mechanical test results showed that modulus increased with higher CNT loading percentages, but the 0.3 wt% CNT-infusion system showed the maximum strength and fracture toughness enhancement. The decrease in strength and fracture toughness in 0.4% CNT/epoxy was attributed to poor dispersions of nanotubes in the composite.
引用
收藏
页码:40 / 48
页数:9
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