Solvent Annealing Induced Perpendicular Orientation of Microdomains in Block Copolymer Thin Films

被引：0

作者：

Yamamoto, Katsuhiro ^{[1
]}

Ohara, Koji ^{[1
]}

Cui, Guanghui ^{[1
]}

Tanaka, Ryo ^{[1
]}

Shimada, Daiki ^{[1
]}

Nagano, Shusaku ^{[2
]}

Sano, Masami ^{[2
]}

Sakurai, Shinichi ^{[3
]}

Shimokita, Keisuke ^{[4
]}

Miyazaki, Tsukasa ^{[4
]}

机构：

[1] Nagoya Inst Technol, Grad Sch Engn, Dept Mat Sci & Engn, Showa Ku, Nagoya, Aichi 4668555, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[3] Kyoto Inst Technol, Grad Sch Sci & Technol, Dept Biobased Mat Sci, Sakyo Ku, Kyoto 6068585, Japan

[4] Nitto Denko Corp, Ibaraki 5678680, Japan

来源：

KOBUNSHI RONBUNSHU | 2014年 / 71卷 / 03期

关键词：

Perpendicular Orientation; Cylindrical Microphase Separated Structure; Grazing Incidence Small Angle X-ray Scattering; Solvent Annealing; Solubility Parameter; CONTROLLED INTERFACIAL INTERACTIONS; X-RAY-SCATTERING; PS-B-PMMA; CYLINDRICAL MICRODOMAINS; DIBLOCK COPOLYMERS; TRANSITION; DOMAINS; ORDER; MORPHOLOGY; ALIGNMENT;

D O I：

10.1295/koron.71.104

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The orientation of cylindrical and lamellar micro-phase separated structures of some block copolymers (BCP) in thin films was investigated by grazing incident small-angle X-ray scattering and atomic force microscopy. The thin films were made from solution using selective solvents for the major component of the BCP. The spherical structure was arrested initially in the film with a thickness of 500 nm(-1) mu m. Solvent annealing, using common solvents, induced a morphology transition from spherical to a vertically oriented cylindrical (lamellar) structure. A neutral solvent for both components in the BCP was found to be effective for the perpendicular orientation of the micro-domains. (C) 2014, The Society of Polymer Science, Japan

引用

页码：104 / 111

页数：8

共 50 条

[21] Cylinder Orientation Mechanism in Block Copolymer Thin Films Upon Solvent Evaporation
Phillip, William A.
Hillmyer, Marc A.
Cussler, E. L.
MACROMOLECULES, 2010, 43 (18) : 7763 - 7770
[22] Solvothermal Annealing of Block Copolymer Thin Films
Gotrik, Kevin W.
Ross, C. A.
NANO LETTERS, 2013, 13 (11) : 5117 - 5122
[23] Perpendicular Orientation of Cylindrical Microdomains in Extruded Triblock Copolymer
Shimizu, Kenichi
Yasuda, Takeshi
Saito, Hiromu
MACROMOLECULES, 2010, 43 (04) : 2088 - 2091
[24] Self-brushing for nanopatterning: achieving perpendicular domain orientation in block copolymer thin films
Feng, Hongbo
Chen, Wen
Craig, Gordon S. W.
Rowan, Stuart J.
Nealey, Paul F.
NANOSCALE, 2024, 16 (17) : 8618 - 8626
[25] Solvent and Substrate Induced Synergistic Ordering in Block Copolymer Thin Films
Modi, Arvind
Karim, Alamgir
Tsige, Mesfin
MACROMOLECULES, 2018, 51 (18) : 7186 - 7196
[26] Thermo-Solvent Annealing of Polystyrene-Polydimethylsiloxane Block Copolymer Thin Films
Dinachali, Saman Safari
Bai, Wubin
Tu, Kun-Hua
Choi, Hong Kyoon
Zhang, Jinshuo
Kreider, Melissa E.
Cheng, Li-Chen
Ross, Caroline A.
ACS MACRO LETTERS, 2015, 4 (05): : 500 - 504
[27] Ordering evolution of block copolymer thin films upon solvent-annealing process
Lee, Dong Hyun
Cho, Heesook
Yoo, Seungmin
Park, Soojin
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 383 : 118 - 123
[28] Film Instability of Amphiphilic Block Copolymer Thin Films Driven by Solvent Annealing and Drying
Sun, Ya-Sen
Chen, Yu-Chung
Liou, Jiun-You
Su, Fan Jun
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2015, 216 (20) : 2020 - 2031
[29] Side-chain-grafted random copolymer brushes as neutral surfaces for controlling the orientation of block copolymer microdomains in thin films
In, Insik
La, Young-Hye
Park, Sang-Min
Nealey, Paul F.
Gopalan, Padma
LANGMUIR, 2006, 22 (18) : 7855 - 7860
[30] Controlled specific placement of nanoparticles into microdomains of block copolymer thin films
Bae, Joonwon
Kim, Jungwook
Park, Jongnam
THIN SOLID FILMS, 2014, 562 : 338 - 342

← 1 2 3 4 5 →