Synthesis of water-soluble fullerene and its isolation

被引：0

作者：

Akimoto, Y ^{[1
]}

Kudo, T ^{[1
]}

Shinoda, K ^{[1
]}

Jeyadevan, B ^{[1
]}

Tohji, K ^{[1
]}

Nirasawa, T ^{[1
]}

Kasuya, A ^{[1
]}

Nishina, Y ^{[1
]}

机构：

[1] Tohoku Univ, Dept Geosci & Technol, Sendai, Miyagi 9808579, Japan

来源：

PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON CLUSTER ASSEMBLED MATERIALS | 2001年 / 3卷

关键词：

water-soluble; fullerene oxide; dimeric fullerene oxide; alkali aqueous solution; HPLC;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report a new and simple method to synthesize water-soluble fullerenes. Here, the fullerene oxides are simply boiled in alkali aqueous solution to obtain water-soluble species. The mass spectrometer of water-soluble sample confirmed the presence of C-60 suggesting the dissolution of the same in water. However, the fourier transform infrared (FT-IR) and ultraviolet-visible (UV-VIS) analysis suggested that the solution contains numerous species and their properties were different to that of C-60. To study the properties of water-soluble species in detail, the isolation using high performance liquid chromatography (HPLC) was attempted. The HPLC analysis of the products suggested the presence of several species of water-soluble fullerene derivatives and in most of the peaks, the presence of C-60 was confirmed. The results of the UV-VIS analysis confirmed the separation of soluble species by HPLC.

引用

页码：123 / 126

页数：4

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