Recovery and Characterization Studies of Post-Production Alloy Waste from the Automotive Industry

被引:2
|
作者
Zelazny, Sylwester [1 ]
Zukowski, Witold [1 ]
Bogdal, Dariusz [2 ]
Bednarz, Szczepan [2 ]
Kasprzyk, Wiktor [2 ]
Swiergosz, Tomasz [3 ]
机构
[1] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Inorgan Chem, Warszawska 24, PL-31155 Krakow, Poland
[2] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Biotechnol & Phys Chem, Warszawska 24, PL-31155 Krakow, Poland
[3] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Analyt Chem, Warszawska 24, PL-31155 Krakow, Poland
关键词
alloy waste; Inconel; 625; 718; Titanium Grade 5; thermal process; washing process; recovery; characterization; surface degradation; NMR; GC; MS; SEM-EDS; CUTTING FLUIDS; OIL; STEEL;
D O I
10.3390/ma13245600
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Superalloys provide high corrosion resistance and are widely used as high-performance materials in aerospace, automotive, chemical, and other industries. Herein, the investigation into the characteristics and properties of alloy waste; Inconel 625, Inconel 718, and Titanium Grade 5, from the automotive industry, was introduced as a result of a recovery in various processes. For this reason, the following procedures were carried as follows; the washing process to remove oil from the swarf was evaluated using several commercial agents and for the process of thermal disposal of processing fluids, a temperature of 900 degrees C was used in a muffle furnace without air access. The presented studies show that the commercially available series of washing agents did not modify the composition of the surface. However, the high temperatures during the calcination of oil residues are affecting the elemental composition of the alloys. According to the results of the analyses, it is not possible to remove 100% of the oil residues from alloy waste using washing agents based on light organic fractions; however, the effectiveness of this method reaches 99%. In this report, accurate SEM-EDS analyses show changes that occur on the surface after machining and removal of processing fluids. The NMR and GC/MS investigations indicate contaminants as a mixture of aliphatic and cycloaliphatic hydrocarbons with carbon numbers from C8-C30.
引用
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页码:1 / 13
页数:13
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