Nanoscale domain structures in 0.91Pb(Zn1/3Nb2/3)O3-0.09PbTiO3 (91PZN-9PT) single crystals studied by piezoresponse forcemicroscopy

被引：1
|
作者：
Rahman, M. Mizanur [1 ]
Metselaar, Hendrik Simon Cornelis [2 ]
Karmaker, Palash Chandra [1 ]
机构：
[1] Univ Informat Technol & Sci, Sch Sci & Engn, Dhaka, Bangladesh
[2] Univ Malaya, Fac Engn, Ctr Adv Mat & Cluster, Kuala Lumpur, Malaysia
来源：
PHASE TRANSITIONS | 2014年 / 87卷 / 04期
关键词：
morphotropic phase boundary; domain patterns; nanodomains; relaxor nature; MORPHOTROPIC PHASE BOUNDARIES; M-C; BEHAVIOR; GROWTH;
D O I：
10.1080/01411594.2013.857410
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
High-resolution domain studies have been performed in 91PZN-9PT single crystals by piezoresponse force microscopy. Nanometer- and micron-sized strip-shaped 180o and parallel 90o domains were observed in the rhombohedral (R) and tetragonal (T) phases. Domain patterns with the typical sizes 5-200nm were observed on the (001)(cub) surface of unpoled sample. The existence of nanodomains in the sample is tentatively attributed to the relaxor nature of PZN-PT where small polar clusters may form under zero-field cooling conditions. The domain observation confirms the structure of the morphotropic 91PZN-9PT crystals, which is composed of both the R and T (or monoclinic) orientations states. The outstanding piezoelectric properties may result from the cooperative response of the microscale/nanoscale domain structure.
引用
收藏
页码：419 / 426
页数：8
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