Shape Selective Chemistries with Modified Mordenite Zeolites

被引:23
|
作者
Garces, Juan M. [1 ,2 ]
Olken, Michael M. [3 ]
Lee, G. John [1 ]
Meima, Garry R. [4 ]
Jacobs, Pierre A. [5 ]
Martens, Johan A. [5 ]
机构
[1] Dow Chem Co USA, Midland, MI 48640 USA
[2] JMG LLC, Midland, MI 48640 USA
[3] Dow Chem, Chem & Catalysis R& D, Midland, MI 48674 USA
[4] Dow Benelux NV, Chem & Catalysis R&D, NL-4530 Terneuzen, Netherlands
[5] Katholieke Univ Leuven, Lab Oppervlaktechem, B-3030 Leuven, Belgium
关键词
Mordenite; 3 DDM catalyst; Mesoporosity; Bifunctional hydro-conversion of n-decane; Alkylation; Trans-alkylation mono; Polynuclear aromatics; MOLECULAR-SIEVE ZEOLITES; NORMAL-DECANE; HYDROCONVERSION; CATALYSTS;
D O I
10.1007/s11244-009-9269-2
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This is a review of work carried at Dow Chemical on the design and characterization of novel mordenite catalysts with a unique micro and meso-porous structure characterized by a variety of methods including, TEM, BET surface area and pore size distribution, and n-decane hydro-conversion. The catalytic performance of these catalysts in shape selective reactions is illustrated with results from n-decane hydro-conversion and applications to alkylation and trans-alkylation reactions of mono and polynuclear aromatic hydrocarbons and other chemistries.
引用
收藏
页码:1175 / 1181
页数:7
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