Aqua[η1-dihydrobis(1,2,4-triazolyl)borato](5,10,15,20-meso-tetraphenylporphyrinato-κ4N)manganese(III) monohydrate

被引：3

作者：

Huh, S ^{[1
]}

Youm, KT

Lough, AJ

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

[3] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804012905

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [Mn(TPP)(eta(1)-H(2)Btz(2))( H2O)] . H2O [where H(2)Btz = dihydrobis(1,2,4-triazolyl) borate, C4H6BN6, and TPP = tetraphenylporphyrin, C44H20N4], contains a singly coordinated H(2)Btz(2). The TPP ligand is highly distorted even though the coordination environment around Mn-III has regular octahedral geometry. Both coordinated and uncoordinated water molecules are involved in intermolecular hydrogen bond through O-H ...O, O-H...N and O - H ...(pi-arene) interactions to form a three-dimensional network.

引用

页码：M895 / M897

页数：3

共 50 条

[31] TRANSITION-METAL COMPLEXES WITH THE NOVEL POLY(1,2,4-TRIAZOLYL)BORATE LIGANDS [HNB(C2H2N3)(4-N)](- (N=1 AND 2) - SYNTHESIS AND CHARACTERIZATION OF METAL-COMPLEXES OF DIHYDROBIS(1,2,4-TRIAZOLYL)BORATE AS ONE-DIMENSIONAL OR 2-DIMENSIONAL COORDINATION POLYMERS WITH 6-MEMBERED RING WATER SUBSTRUCTURES AND THE STRUCTURE OF 2-DIMENSIONAL LIQUID AND SOLID WATER AS ORGANIZED IN THE INTERCALATE [NI(HB(C2H2N3)(3))(2)]CENTER-DOT-6H2O (X-RAY STUDIES AT 293-K AND 160-K)
JANIAK, C
SCHARMANN, TG
HEMLING, H
LENTZ, D
PICKARDT, J
[J]. CHEMISCHE BERICHTE-RECUEIL, 1995, 128 (03): : 235 - 244
[32] Crystal structure of aqua (5,5′-dicarboxy-(1,1′-biphenyl)-2,3′-dicarboxylato-κO) bis(1,10-phenanthroline-κ2N, N′) cadmium monohydrate, C40H28CdN4O10
Yao, Li-Ping
Zhao, Yan
Zhang, Rui
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2016, 231 (04): : 1017 - 1019
[33] Crystal structure of (methanol-kappa O)[5,10,15,20-tetrakis(2-aminophenyl)porphyrinato-kappa N-4]zinc(II)-chloroform-methanol (1/1/1)
Leben, Lisa
Naeher, Christian
Herges, Rainer
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1285 - +
[34] 1D and 2D solid-state metallosupramolecular arrays of freebase 5,10,15,20-tetra(4-pyridyl)porphyrin, peripherally linked by zinc and manganese ions
Seidel, Rudiger W.
Oppel, Iris M.
[J]. STRUCTURAL CHEMISTRY, 2009, 20 (01) : 121 - 128
[35] 1D and 2D solid-state metallosupramolecular arrays of freebase 5,10,15,20-tetra(4-pyridyl)porphyrin, peripherally linked by zinc and manganese ions
Rüdiger W. Seidel
Iris M. Oppel
[J]. Structural Chemistry, 2009, 20 : 121 - 128
[36] Molecular structures of Ge(tpp)(OAc)(2) and In(tpp)(OAc) and their implications: Correlations between the C-13 NMR chemical shift of the acetato ligand and different types of carboxylate coordination in M(por)(OAc)(n) {por=tpp (5,10,15,20-tetraphenylporphyrinate), tmpp (5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate), tpyp (5,10,15,20-tetrakis(4-pyridyl)porphyrinate); M=Ga, In, Tl, Ge, Sn; n=1, 2}
Lin, SWJA
Hong, TN
Tung, JY
Chen, JHR
[J]. INORGANIC CHEMISTRY, 1997, 36 (18) : 3886 - 3891
[37] The crystal structure of dimethanol-κ1O-(5,10,15,20-tetrakis(4-nitrophenyl)porphyrin-21,23-diido-κ4 O,O′,O",O")manganese(III) trans-dicyanido-κ1C-bis(acetylacetonato-κ2 O,O′)ruthenium(III), C58H46N10O14RuMn
Zhou, Tingting
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2022, 237 (06): : 1071 - 1073
[38] Synthesis, crystal structure and vibrational spectroscopic analysis of tetrakis(5-amino-1-H-1,2,4-triazol-4-ium) decachlorodibismuthate(III):[C2H5N4]4Bi2Cl10
Aloui, Z.
Ferretti, V.
Abid, S.
Lefebvre, F.
Rzaigui, M.
Ben Nasr, C.
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2015, 1097 : 166 - 170
[39] The crystal structure of (azido)-κ1N-6,6′-((cyclohexane-1,2-diylbis(azanytylidene)) bis(methanytylidene))bis(3-bromophenolato-κ4N,N,O,O)-(methanol)-manganese(III) methanol(1/1), C22H26Br2MnN5O4
Liu, Dian
Ma, Xun
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2021, 236 (03): : 623 - 625
[40] Crystal structure of [aqua[2,2′-(1,2-phenylene)bis (1H-imidazole-4-carboxylato-5-carboxy)-κ4N3,N3′,O4,O4′] zinc(II)] monohydrate, C16H10N4O9Zn•H2O
Wang, Wen-Bin
Shi, Xin-Chang
Li, Ying-Ying
Cheng, Fang-Rong
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (06): : 1133 - 1135

← 1 2 3 4 5 →