Aqua[η1-dihydrobis(1,2,4-triazolyl)borato](5,10,15,20-meso-tetraphenylporphyrinato-κ4N)manganese(III) monohydrate

被引：3

作者：

Huh, S ^{[1
]}

Youm, KT

Lough, AJ

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

[3] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804012905

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [Mn(TPP)(eta(1)-H(2)Btz(2))( H2O)] . H2O [where H(2)Btz = dihydrobis(1,2,4-triazolyl) borate, C4H6BN6, and TPP = tetraphenylporphyrin, C44H20N4], contains a singly coordinated H(2)Btz(2). The TPP ligand is highly distorted even though the coordination environment around Mn-III has regular octahedral geometry. Both coordinated and uncoordinated water molecules are involved in intermolecular hydrogen bond through O-H ...O, O-H...N and O - H ...(pi-arene) interactions to form a three-dimensional network.

引用

页码：M895 / M897

页数：3

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