Engineering a pillar[5]arene-based supramolecular organic framework by a co-crystallization method

被引：0

作者：

Wang, Guo ^{[1
,2
,3
]}

Hu, Wei-Bo ^{[1
]}

Zhao, Xiao-Li ^{[4
,5
]}

Liu, Yahu A. ^{[6
]}

Li, Jiu-Sheng ^{[1
]}

Jiang, Biao ^{[1
]}

Wen, Ke ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China

[2] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100039, Peoples R China

[4] East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[5] East China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China

[6] ChemBridge Res Labs, Med Chem, San Diego, CA 92127 USA

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 15期

基金：

上海市自然科学基金; 中国国家自然科学基金;

关键词：

HIGH-YIELD SYNTHESIS; MOLECULAR RECOGNITION; PHARMACEUTICAL COCRYSTALS; CO2; ADSORPTION; WATER; VESICLES; AMPHIPHILE; STABILITY; GAS; NANOPARTICLES;

D O I：

10.1039/c8dt00566d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A supramolecular organic framework, P5-bpy-SOF, made of perhydroxyl-pillar[5]arene (P5) and 4,4-bipyridine (bpy) and prepared by using a co-crystallization approach, showed a different hydrogen bonding pattern and a 3D molecular arrangement from that in the perhydroxyl-pillar[5]arene-based supramolecular organic framework (P5-SOF). TGA analyses, powder X-ray diffraction and gas absorption study confirmed P5-bpy-SOF's structural stability, permanent porosity, and, especially, selectivity of absorption of CO2 over N-2.

引用

页码：5144 / 5148

页数：5

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