Green Synthesis of Haloformates from Olefins Using Formic Acid as Reactant, Protonic Acid, and Solvent

被引：4

作者：

Wang, Ligeng ^{[1
]}

Zhang, Hualong ^{[1
]}

Yu, Qin ^{[1
]}

Feng, Chun ^{[1
]}

Hu, Jun ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China

来源：

SYNLETT | 2018年 / 29卷 / 12期

关键词：

olefins; formic acid; bromoformates; iodoformates; regioselectivity; stereoselectivity; BROMO-FORMYLOXYLATION; N-HALOAMIDE; BROMINATION; ALKENES; N; N-DIBROMOBENZENESULFONAMIDE; BROMOFORMYLOXYLATION; BROMOACETOXYLATION; TRANSFORMATION; BROMOHYDRINS; OXIDATION;

D O I：

10.1055/s-0037-1610028

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bromoformates and iodoformates are successfully synthesized in high yields with regioselectivity and stereoselectivity by using ZnAl- BrO3 - layered double hydroxides ( LDHs) and KX ( X = Br, I) in the presence of formic acid ( HCOOH). The protocol exploits the versatile function of formic acid as solvent, nucleophilic reagent, and acidic medium simultaneously, simplifying the reaction and separation of the products.

引用

页码：1611 / 1616

页数：6

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