Synthesis, spectroscopic characterization, and X-ray crystal structure of tris(trimethylsilyl)cyanurate

被引：2
|
作者：
El-Gamel, Nadia E. A. [1 ]
Brand, Joerg [2 ]
Kroke, Edwin [3 ]
机构：
[1] Cairo Univ, Fac Sci, Dept Chem, Giza 12613, Egypt
[2] Univ Konstanz, Dept Chem, D-78457 Constance, Germany
[3] Tech Univ Bergakad Freiberg, Inst Anorgan Chem, D-09596 Freiberg, Germany
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 08期
关键词：
S-triazine; Tri-s-triazine; FTIR and Raman spectra; NMR; Thermal behavior; X-ray crystal structure; TRI-S-TRIAZINE; CYANURIC ACID; DERIVATIVES; INTERMEDIATE; CHEMISTRY; POLYMERS;
D O I：
10.1080/00958970802499372
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tris(trimethylsilyl)cyanurate, C12H27N3O3Si3 (1), has been synthesized and characterized by elemental analysis, IR, Raman, 13C and 29Si NMR, and thermogravimetric methods. The molecular and crystal structure has been determined by single crystal X-ray diffraction. This compound crystallized in space group P63/m (176), Z = 2 with a = 11.017(2), b = 11.017(2), c = 9.676(3) ; = 90, = 90, = 120. The geometry of the molecule is compared with tris(trimethylsilyl)cyamelurate.
引用
收藏
页码：1278 / 1284
页数：7
相关论文
共 50 条
  • [21] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF TRIS(PHENYLDI-ISOPROPYLPHOSPHINE)-TUNGSTEN HEXAHYDRIDE
    GREGSON, D
    HOWARD, JAK
    NICHOLLS, JN
    SPENCER, JL
    TURNER, DG
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (12) : 572 - 573
  • [22] SYNTHESIS AND X-RAY STRUCTURE OF BISTETRAPHENYLPHOSPHONIUM TRIS(PHENYLSULPHONYLIMINO)SULPHITE
    ROESKY, HW
    SCHMIEDER, W
    SHELDRICK, WS
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (19) : 1013 - 1014
  • [23] X-RAY CRYSTAL-STRUCTURE AND PROPERTIES OF TRIS(TETRATHIAFULVALENIUM) HEXACHLOROPLATINATE
    UEYAMA, K
    MATSUBAYASHI, GE
    TANAKA, T
    INORGANICA CHIMICA ACTA, 1986, 112 (02) : 135 - 137
  • [24] A new supramolecular compound of chrome(III): Synthesis, spectroscopic characterization, X-ray crystal structure, DFT, and solution studies
    Eshtiagh-Hosseini, Hossein
    Yousefi, Zakieh
    Mirzaei, Masoud
    Chen, Ya-Guang
    Beyramabadi, S. Ali
    Shokrollahi, Ardeshir
    Aghaei, Roghayyeh
    JOURNAL OF MOLECULAR STRUCTURE, 2010, 973 (1-3) : 1 - 8
  • [25] SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURE OF A TRIMETALLIC DIPORPHYRIN COMPLEX
    WOO, LK
    MAURYA, MR
    JACOBSON, RA
    RINGROSE, SL
    INORGANICA CHIMICA ACTA, 1993, 212 (1-2) : 337 - 340
  • [26] Synthesis, optical characterization and crystal and molecular X-ray structure of a phenylazojulolidine derivative
    Barbero, Nadia
    Barolo, Claudia
    Marabello, Domenica
    Buscaino, Roberto
    Gervasio, Giuliana
    Viscardi, Guido
    DYES AND PIGMENTS, 2012, 92 (03) : 1177 - 1183
  • [27] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE CHARACTERIZATION OF AMMONIA-CYANOBORANE
    MCPHAIL, AT
    ONAN, KD
    SPIELVOGEL, BF
    WISIANNEILSON, P
    JOURNAL OF CHEMICAL RESEARCH-S, 1978, (06): : 205 - &
  • [28] A novel terpyridyl rhenium(II) complex - Synthesis, spectroscopic characterization and X-ray structure
    Machura, B.
    Kruszynski, R.
    Kusz, J.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (08) : 918 - 920
  • [29] X-Ray Crystal Structure Determination and Spectroscopic Characterization of trans-Diamminedihydroxoplatinum(II) Dihydrate
    Acta Chemica Scandinavica, 50 (02):
  • [30] X-ray crystal structure determination and spectroscopic characterization of trans-diamminedihydroxoplatinum(II) dihydrate
    Arpalahti, J
    Sillanpaa, R
    Barnham, KJ
    Sadler, PJ
    ACTA CHEMICA SCANDINAVICA, 1996, 50 (02): : 181 - 184
12345