Synthesis, spectroscopic characterization, and X-ray crystal structure of tris(trimethylsilyl)cyanurate

被引：2
|
作者：
El-Gamel, Nadia E. A. [1 ]
Brand, Joerg [2 ]
Kroke, Edwin [3 ]
机构：
[1] Cairo Univ, Fac Sci, Dept Chem, Giza 12613, Egypt
[2] Univ Konstanz, Dept Chem, D-78457 Constance, Germany
[3] Tech Univ Bergakad Freiberg, Inst Anorgan Chem, D-09596 Freiberg, Germany
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 08期
关键词：
S-triazine; Tri-s-triazine; FTIR and Raman spectra; NMR; Thermal behavior; X-ray crystal structure; TRI-S-TRIAZINE; CYANURIC ACID; DERIVATIVES; INTERMEDIATE; CHEMISTRY; POLYMERS;
D O I：
10.1080/00958970802499372
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tris(trimethylsilyl)cyanurate, C12H27N3O3Si3 (1), has been synthesized and characterized by elemental analysis, IR, Raman, 13C and 29Si NMR, and thermogravimetric methods. The molecular and crystal structure has been determined by single crystal X-ray diffraction. This compound crystallized in space group P63/m (176), Z = 2 with a = 11.017(2), b = 11.017(2), c = 9.676(3) ; = 90, = 90, = 120. The geometry of the molecule is compared with tris(trimethylsilyl)cyamelurate.
引用
收藏
页码：1278 / 1284
页数：7
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