Kinetic nonuniformity in complex-radical polymerization of styrene in the presence of metallocene initiating systems

被引：0

作者：

Sigaeva, NN ^{[1
]}

Kolesov, SV ^{[1
]}

Abdulgalimova, AU ^{[1
]}

Garifullina, RN ^{[1
]}

Prokudina, EM ^{[1
]}

Spivak, SI ^{[1
]}

Budtov, VP ^{[1
]}

Monakov, YB ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Sci Ctr, Inst Organ Chem, Ufa 450054, Bashkortostan, Russia

来源：

POLYMER SCIENCE SERIES A | 2004年 / 46卷 / 08期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

For the free-radical polymerization of styrene initiated by metallocene systems, kinetic nonuniformity distributions of active centers are estimated based on experimentally derived molecular mass distribution curves using the Tikhonov regularization method. The polymodal pattern of the kinetic nonuniformity distribution curves indicates the existence of two types of active centers that change their kinetic activity during polymerization.

引用

页码：784 / 789

页数：6

共 50 条

[41] Radical bulk polymerization of styrene in the presence of fullerene[60]
Arsalani, N
Geckeler, KE
FULLERENE SCIENCE AND TECHNOLOGY, 1996, 4 (05): : 897 - 912
[42] Radical polymerization of styrene in the presence of C60
Chen, Y
Lin, KC
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999, 37 (15) : 2969 - 2975
[43] Radical polymerization of methyl methacrylate and styrene in the presence of ferrocene
Puzin, YI
Yumagulova, RK
Kraikin, VA
EUROPEAN POLYMER JOURNAL, 2001, 37 (09) : 1801 - 1812
[44] Controlled radical polymerization of styrene in the presence of molecular iodine
D. I. Shiman
S. V. Kostyuk
L. V. Gaponik
F. N. Kaputskii
Russian Journal of Applied Chemistry, 2010, 83 : 2028 - 2034
[45] Controlled Radical Polymerization of Styrene in the Presence of Molecular Iodine
Shiman, D. I.
Kostyuk, S. V.
Gaponik, L. V.
Kaputskii, F. N.
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2010, 83 (11) : 2028 - 2034
[46] RADICAL POLYMERIZATION OF STYRENE IN PRESENCE OF AROMATIC NITROSO COMPOUNDS
YONEDA, A
TANAKA, M
MURATA, N
CHEMISTRY OF HIGH POLYMERS, 1970, 27 (300): : 269 - &
[47] FEATURES OF RADICAL POLYMERIZATION OF STYRENE AND METHACRYLATES IN THE PRESENCE OF COBALOXIMES
GRIDNEV, AA
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1989, 31 (10): : 2153 - 2159
[48] A novel photo-initiating system for atom transfer radical polymerization of styrene
Qin, Shu-Hui
Qin, Dong-Qi
Qiu, Kun-Yuan
Chinese Journal of Polymer Science (English Edition), 2001, 19 (05): : 441 - 445
[49] A novel photo-initiating system for atom transfer radical polymerization of styrene
Qin, SH
Qin, DQ
Qiu, KY
CHINESE JOURNAL OF POLYMER SCIENCE, 2001, 19 (05) : 441 - 445
[50] INITIATING ACTION OF PEROXIDE DERIVATIVES OF M-CARBORANE AT RADICAL POLYMERIZATION OF STYRENE
KONOVALENKO, VV
SHUMNYI, LV
NIKULINA, YN
CHURKINA, LA
ZVEREVA, TD
OLDEKOP, YA
IVANCHEV, SS
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1980, 22 (06): : 432 - 436

← 1 2 3 4 5 →