Kinetic nonuniformity in complex-radical polymerization of styrene in the presence of metallocene initiating systems

被引：0

作者：

Sigaeva, NN ^{[1
]}

Kolesov, SV ^{[1
]}

Abdulgalimova, AU ^{[1
]}

Garifullina, RN ^{[1
]}

Prokudina, EM ^{[1
]}

Spivak, SI ^{[1
]}

Budtov, VP ^{[1
]}

Monakov, YB ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Sci Ctr, Inst Organ Chem, Ufa 450054, Bashkortostan, Russia

来源：

POLYMER SCIENCE SERIES A | 2004年 / 46卷 / 08期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

For the free-radical polymerization of styrene initiated by metallocene systems, kinetic nonuniformity distributions of active centers are estimated based on experimentally derived molecular mass distribution curves using the Tikhonov regularization method. The polymodal pattern of the kinetic nonuniformity distribution curves indicates the existence of two types of active centers that change their kinetic activity during polymerization.

引用

页码：784 / 789

页数：6

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