Chemical clock reactions: The effect of precursor consumption

被引：9
|
作者：
Preece, SJ [1 ]
Billingham, J [1 ]
King, AC [1 ]
机构：
[1] Univ Birmingham, Sch Math & Stat, Birmingham B15 2TT, W Midlands, England
来源：
JOURNAL OF MATHEMATICAL CHEMISTRY | 1999年 / 26卷 / 1-3期
关键词：
Induction Period; Asymptotic Solution; Asymptotic Estimate; Parameter Limit; Asymptotic Region;
D O I：
10.1023/A:1019121525203
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
During a clock reaction an initial induction period is observed before a significant change in concentration of one of the chemical species occurs. In this study we develop the results of Billingham and Needham (1993) who studied a particular class of inhibited autocatalytic clock reactions. We obtain modified expressions for the length of the induction period and show that characteristic clock reaction behaviour is only observed within certain parameter limits.
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页码：47 / 73
页数：27
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