Pd(II)-catalyzed C-H arylation of aryl and benzyl Weinreb amides

被引：22

作者：

Wang, Yan ^{[1
]}

Zhou, Kai ^{[1
]}

Lan, Quan ^{[1
]}

Wang, Xi-Sheng ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 02期

关键词：

CATALYZED ORTHO-ARYLATION; BOND FUNCTIONALIZATION; ROOM-TEMPERATURE; NATURAL-PRODUCTS; DIRECTING GROUP; PALLADIUM; ACTIVATION; STRATEGY; IODIDES; UREAS;

D O I：

10.1039/c4ob02039a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first example of palladium-catalyzed ortho-C-H arylation of aryl and benzyl Weinreb amides was developed, in which HOTf was used as a key promoter. This method exhibits good functional group tolerance, a broad substrate scope of both Weinreb amides and aryl iodides, high mono-selectivity and mild reaction conditions.

引用

页码：353 / 356

页数：4

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