Intramolecular cyclization of 1,3-diamino-2-hydroxypropan-N,N,NA′,NA′-tetrakis(methylphosphonic acid) upon phosphonomethylation of 1,3-diaminopropan-2-ol

被引：4
|
作者：
Tsirul'nikova, N. V. [1 ]
Bolt, Ya. V. [1 ]
Belus, S. K. [1 ]
机构：
[1] State Sci Res Inst Chem Reagents & High Pur Chem, 3 Ul Bogorodsky Val, Moscow 107076, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 05期
关键词：
1,3-diaminopropan-2-ol; phosphonomethylation; NMR spectroscopy; 1,3-di-amino-2-hydroxypropan-N,N,N ',N '-tetrakis(methylphosphonic acid); cyclic ester;
D O I：
10.1007/s11172-015-1001-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Phosphonomethylation of 1,3-diaminopropan-2-ol affords the mixture of 1,3-diamino-2-hydroxypropan-N,N,NA ',NA '-tetrakis(methylphosphonic acid) (1) with its cyclic ether, viz., [(6-[bis(phosphonomethyl)amino]methyl-2-hydroxy-2-oxido-1,4,2-oxazaphosphinan-4-yl)methyl]phosphonic acid (2), but not 1, as assumed earlier.
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页码：1200 / 1201
页数：2
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