Syntheses and structures of two rhenium-sulfur-copper cubane-like cluster compounds with the bridging sulfate anions

被引：3

作者：

Shi, Hua-Tian ^{[1
]}

Xu, Chao ^{[1
]}

Jia, Ai-Quan ^{[1
]}

Huang, Xiang-Hong ^{[3
]}

Zhang, Qian-Feng ^{[1
,2
]}

机构：

[1] Anhui Univ Technol, Inst Mol Engn & Appl Chem, Maanshan 243002, Anhui, Peoples R China

[2] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[3] Zhejiang Shuren Univ, Coll Biol & Environm Engn, Hangzhou 310015, Zhejiang, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2014年 / 419卷

基金：

中国国家自然科学基金;

关键词：

Heterobimetallic compound; Rhenium-sulfur-copper cluster; Thiometalate; Sulfate anion; Crystal structure; X-RAY-STRUCTURE; TECHNETIUM NITROSYL COMPLEX; ELECTRON-PARAMAGNETIC-RES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; LIGANDS; PHOSPHINES; PHOSPHANES; BEHAVIOR; GOLD(I);

D O I：

10.1016/j.ica.2014.04.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [Et4N][ReS4] with three equivalents of CuSO4 center dot 5H(2)O in the presence of three equivalents PPh3 gave a tetranuclear cubane-like cluster compound [(mu(3)-SO4)(mu(3)-ReS4)Cu-3(PPh3)(3)]center dot 2dmf(1 center dot 2dmf) in which a ReS4Cu3 core is capped by a mu(3)-SO42 moiety, leaving a S=O double bond. A similar reaction of [Et4N][ReS4] with three equivalents of CuSO4 center dot 5H(2)O in the presence of two equivalents of PPh3 gave rise to isolation of a neutral one-dimensional polymeric cubane-like cluster compound [(mu(4)-SO4)(mu(3)-ReOS3)Cu-3(PPh3)(2)](n) (2) in which the ReOS3Cu3 cores are bridged by the mu(4)-SO42 anions. Both cluster compounds were characterized by single-crystal X-ray diffraction along with the spectroscopic methods. (C) 2014 Published by Elsevier B.V.

引用

页码：55 / 65

页数：11

共 35 条

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