Sex pheromone of the pine sawfly Macrodiprion nemoralis (Hymenoptera: Diprionidae):: Identification of (2S,3R,7R,9S)-3,7,9-trimethyl-2-tridecanol as the precursor for the active pheromone acetate

被引：22
|
作者：
Wassgren, AB
Bergström, G
Sierpinski, A
Anderbrant, O
Högberg, HE
Hedenström, E
机构：
[1] Mid Sweden Univ, Dept Chem & Proc Technol, S-85170 Sundsvall, Sweden
[2] Univ Gothenburg, Dept Bot, S-40530 Gothenburg, Sweden
[3] Forestry Res Inst Warsaw, PL-00973 Warsaw, Poland
[4] Lund Univ, Dept Ecol, S-22362 Lund, Sweden
来源：
NATURWISSENSCHAFTEN | 2000年 / 87卷 / 01期
关键词：
D O I：
10.1007/s001140050003
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The main component of the sex pheromone precursor in females of Macrodiprion nemoralis was identified as a threo-3,7,9-trimethyl-2-tridecanol isomer, approximately 800 pg per female, by gas chromatography-mass spectrometry. Comparison of mass spectrometric ion chromatograms showed that the natural compound in the female extract has the same retention time and mass spectrum as one of the two synthetic three peaks. The acetate of the synthetic 16-isomer mixture caught a large number of males in the field. confirming the structure of the active pheromone. Comparison of gas chromatograms of the natural female extract with the eight synthetic three stereoisomers showed that the pheromone is the (2S,3R,7R,9S)-stereoisomer of 3,7,9-trimethyl-2-tridecyl acetate.
引用
收藏
页码：24 / 29
页数：6
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