Synthesis, electrochemistry, Langmuir-Blodgett deposition and photophysics of metal-coordinated fullerene-porphyrin dyads

被引：39
|
作者：
Da Ros, T
Prato, M
Carano, M
Ceroni, P
Paolucci, F
Roffia, S
Valli, L
Guldi, DM
机构：
[1] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy
[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[3] Dipartimento Ingn Innovaz, Edificio La Stecca, I-73100 Lecce, Italy
[4] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46656 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 599卷 / 01期
关键词：
fullerenes; ruthenium; porphyrin; Langmuir-Blodgett; photophysics;
D O I：
10.1016/S0022-328X(99)00754-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel fullerene-Ru-porphyrin conjugate (3b) for Langmuir-Blodgett (LB) film deposition has been synthesized. The side polar chain that characterizes the complex is necessary to introduce enough amphiphilicity in these otherwise non-polar moieties. The complex can be deposited on solid substrates via the LB technique and the films obtained show charge separation upon light irradiation. In addition, a careful cyclic voltammetry study of the complex is reported. (C) 2000 Elsevier Science S.A, All rights reserved.
引用
收藏
页码：62 / 68
页数：7
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