Gold-catalyzed olefin cyclopropanation

被引：92
|
作者：
Prieto, Auxiliadora [2 ]
Fructos, Manuel R. [1 ]
Mar Diaz-Requejo, M. [1 ]
Perez, Pedro J. [1 ]
Perez-Galan, Patricia [3 ]
Delpont, Nicolas [3 ]
Echavarren, Antonio M. [3 ]
机构：
[1] Univ Huelva, CSIC, Unidad Asociada, Dept Quim & Ciencia Mat,Lab Catalisis Homogenea, Huelva 21007, Spain
[2] Univ Huelva, Dept Ingn Quim Quim Fis & Quim Organ, Huelva 21007, Spain
[3] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
来源：
TETRAHEDRON | 2009年 / 65卷 / 09期
关键词：
FUNCTIONALIZATION; ALKENES; COMPLEXES; INSERTION;
D O I：
10.1016/j.tet.2008.10.114
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The selectivity of the cyclopropanation of olefins with ethyl phenyldiazoacetate has been tested using different gold complexes bearing phosphine, phosphite or N-heterocyclic as ligands. A comparative study with related copper and silver complexes as catalysts is also presented. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1790 / 1793
页数：4
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