Di-tert-butylcyclopentadienyl complexes of europium and ytterbium:: synthesis and crystal structures of (1,3-Bu(t)2C5H3)2Eu•THF, (1,3-Bu(t)2C5H3)(C5Me5)Yb•THF, and (1,3-Bu(t)2C5H3)2Yb(μ2-Cl)2Li(THF)2

被引：0

作者：

Khvostov, AV

Bulychev, BM

Belsky, VK

Sizov, AI

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Russian Federat L Ya Karpov Sci Res Physicochem I, State Res Ctr, Moscow 103064, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 11期

关键词：

europium(+2); ytterbium; metallocenes; crystal structure;

D O I：

10.1007/BF02494868

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The (1,3-(Bu2C5H3)-C-t)(2)Eu . THF complex was prepared by the reaction of 1,3-(Bu2C5H3Na)-C-t with EuI2 in tetrahydrofuran. The mixed-ligand (1,3-(Bu2C5H3)-C-t)(C5Me5)Yb . THF complex was obtained by the reaction of YbI2 with C5Me5Na and 1,3-(Bu2C5H3Na)-C-t. The reaction of 1,3-(Bu2C5H3Li)-C-t with YbCl3 afforded the (1,3-(Bu2C5H3)-C-t)(2)Yb(mu(2)-Cl)(2)Li(THF)(2) ate-complex. The structures of the title compounds were established by X-ray diffraction analysis.

引用

下载

页码：2162 / 2166

页数：5

共 50 条

[31] SYNTHESIS AND CRYSTAL-STRUCTURE OF ([(C5H9C5H4)ER(THF)]2(MU-2-CL)3(MU-3-CL)2NA(THF)2).THF
JIN, JZ
JIN, SC
JIN, ZS
CHEN, WQ
POLYHEDRON, 1992, 11 (22) : 2873 - 2876
[32] Intrinsic reactivity of [η5-1,3-(Me3Si)2C5H3]2∨(η4-C4Ph2) in small molecule activation
Wang, Shichun
Heng, Yi
Li, Tongyu
Wang, Dongwei
Hou, Guohua
Zi, Guofu
Walter, Marc D.
DALTON TRANSACTIONS, 2022, 51 (29) : 11072 - 11085
[33] SYNTHESIS AND STRUCTURE OF MONO-THF SOLVATES OF BIS(CYCLOPENTADIENYL)SAMARIUM(II) COMPLEXES - (C5ME5)2SM(THF) AND [C5H2(SIME3)3][C5H3(SIME3)2]SM(THF)
EVANS, WJ
KOCIOKKOHN, G
FOSTER, SE
ZILLER, JW
DOEDENS, RJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 444 (1-2) : 61 - 66
[34] CRYSTAL-STRUCTURE OF ORGANOLANTHANIDE COMPLEXES [LI(THF)2]2(MU-CL)4(ETA-5-C5H5)LA.THF, [LI(THF)2]2(MU-CL)4(ETA-5-C5H5)ND.THF
JIN, ZS
HU, NH
LI, Y
XU, XL
LIU, GZ
INORGANICA CHIMICA ACTA, 1988, 142 (02) : 333 - 336
[35] Lutetium complexes with the 1,3-diphenylcyclopentadienyl ligand.: Syntheses and molecular structures of the complexes {(Ph2C5H3)Lu(C2Ph4)(THF)} and {(Ph2C5H3)LuCl2(THF)3}
Roitershtein, D. M.
Minyaev, M. E.
Mikhailyuk, A. A.
Lyssenko, K. A.
Belyakov, P. A.
Antipin, M. Yu.
RUSSIAN CHEMICAL BULLETIN, 2007, 56 (10) : 1978 - 1985
[36] Lutetium complexes with the 1,3-diphenylcyclopentadienyl ligand. Syntheses and molecular structures of the complexes {(Ph2C5H3)Lu(C2Ph4)(THF)} and {(Ph2C5H3)LuCl2(THF)3}
D. M. Roitershtein
M. E. Minyaev
A. A. Mikhailyuk
K. A. Lyssenko
P. A. Belyakov
M. Yu. Antipin
Russian Chemical Bulletin, 2007, 56 : 1978 - 1985
[37] HALF-SANDWICH PYRAZOLYLBORATE COMPLEXES OF THE LANTHANIDES - THE MOLECULAR-STRUCTURES OF [YB(HB(3-BU(T)-5-ME-PYRAZOLYL)(3))I(THF)] AND [YB(HB(3BU(T)-5-ME-PYRAZOLYL)(3))I-(3,5-LUTIDINE)(2)]
MAUNDER, GH
SELLA, A
TOCHER, DA
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (23) : 2689 - 2690
[38] STRUCTURAL DIVERSITY IN BIS(PENTAMETHYLCYCLOPENTADIENYL)YTTRIUM CHLORIDE COMPLEXES - COCRYSTALLIZATION OF [(C5ME5)2Y(MU-CL)2LI(THF)2] AND [(C5ME5)2YCL(MU-CL)LI(THF)3]
EVANS, WJ
BOYLE, TJ
ZILLER, JW
INORGANIC CHEMISTRY, 1992, 31 (06) : 1120 - 1122
[39] Yttrium and Lithium Keto-β-Diketiminate Complexes [{2,6-Me2C6H3N=C(Me)}2CС(tert-Bu)=O]2Y(μ2-Cl)2Li(THF)2 and {[{2,6-Me2C6H3N=C(Me)}2CС(tert-Bu)=O]Li(THF)}n. Synthesis, Molecular Structures, and Catalytic Activity in ε-Caprolactone Polymerization
G. G. Skvortsov
A. V. Cherkasov
D. L. Vorozhtsov
E. S. Shchegravina
A. A. Trifonov
Russian Journal of Coordination Chemistry, 2021, 47 : 144 - 154
[40] Triphospha-ferrocenes as ligands. Crystal structures of [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))M(CO)(5))], (M=Cr,Mo,W) and the novel ruthenium and nickel complexes [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))Ru-3(CO)(9)] and [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))Ni(CO)(2)](2)
Bartsch, R
Muller, C
Fischer, A
Jones, PG
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1996, 111 (1-4): : 684 - 684

← 1 2 3 4 5 →