Pentamethylcyclopentadienyl rhodium and iridium complexes containing oxinato ligands

被引：18
|
作者：
Thai, Trieu-Tien [1 ]
Therrien, Bruno [1 ]
Suess-Fink, Georg [1 ]
机构：
[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 08期
基金：
瑞士国家科学基金会;
关键词：
Rhodium; Iridium; Pentamethylcyclopentadienyl; Oxinato;
D O I：
10.1016/j.inoche.2009.06.023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The neutral chloror complexes [(eta(5)-C5Me5)M(eta(2)-NC9H6O)Cl] as well as the cationic aqua complexes [(eta 5-C5Me5)M(eta(2) -NC9H6O)(H2O)](+) (M = Rh, Ir) have been synthesized from the reaction of the dinuclear precursors [eta(5)-C5Me5)MCl2](2) and 8-hydroxyquinoline. The single crystal X-ray structure analysis of [(eta(5)-C5Me5)Ir(eta(2)-NC9H6O)Cl] reveals for these complexes a piano-stool arrangement with the aromatic ligand, the chelating oxinato ligand and the terminal chloro or aqua ligand surrounding the metal center in a pseudo-tetrahedral fashion. (C) 2009 Elsevier B.V. All rights reserved.
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页码：806 / 807
页数：2
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