Catalyst-free, visible-light-promoted S-H insertion reaction between thiols and α-diazoesters

被引：29

作者：

Yang, Jingya ^{[1
]}

Wang, Ganggang ^{[1
]}

Chen, Shuwen ^{[1
]}

Ma, Ben ^{[1
]}

Zhou, Hongyan ^{[1
,2
]}

Song, Menghui ^{[1
]}

Liu, Cai ^{[1
]}

Huo, Congde ^{[1
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China

[2] Gansu Agr Univ, Coll Sci, Lanzhou 730070, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 46期

基金：

中国国家自然科学基金;

关键词：

BOND FORMATION; DIAZO-COMPOUNDS; C-S; ETHYL DIAZOACETATE; CARBENE-TRANSFER; N-H; METAL; FUNCTIONALIZATION; ACTIVATION; THIOETHERS;

D O I：

10.1039/d0ob02006k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A visible-light-promoted S-H insertion reaction between thiols and alpha -diazoesters was developed. The reaction proceeded smoothly at room temperature with a broad substrate scope, affording various thioethers in moderate to excellent yields. The catalyst- and additive-free nature, sustainable energy source and mild reaction conditions make this strategy more eco-friendly.

引用

页码：9494 / 9498

页数：5

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