Asymmetric total synthesis of (+)-carneic acid A and structure revision of its natural form

被引：10

作者：

Yamakoshi, Shuhei ^{[1
]}

Hayashi, Nobuyuki ^{[1
]}

Suzuki, Takahiro ^{[1
]}

Nakada, Masahisa ^{[1
]}

机构：

[1] Waseda Univ, Fac Sci & Engn, Dept Chem & Biochem, Shinjuku Ku, Tokyo 1698555, Japan

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 38期

关键词：

(+)-PHOMOPSIDIN; OXIDATION; REAGENTS;

D O I：

10.1016/j.tetlet.2009.07.024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This Letter describes the asymmetric total synthesis of (+)-carneic acid A via the stereoselective IMDA reaction of (E,E,E)-triene, which was prepared from the commercially available methyl (S)-3-hydroxy-2-methylpropionate. By this asymmetric total synthesis, we verified that the reported absolute structure of naturally occurring carneic acid A must be revised. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：5372 / 5375

页数：4

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