Synthesis and properties of lanthanide(III) complexes containing pyridine-substituted imino nitroxide radical

被引：0

作者：

Tsukuda, T ^{[1
]}

Suzuki, T ^{[1
]}

Kaizaki, S ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Osaka 5600043, Japan

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2002年 / 379卷

关键词：

lanthanide; imino nitroxide radical; crystal structures; magnetic interaction;

D O I：

10.1080/713738676

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Some lanthanide(III) complexes containing three types of a chelated n-methylpyridine-substituted imino nitroxide radical IMnMe2py(n=4,5,6) were synthesized with a small size of the multi-spin system. X-ray structural analysis of [Gd(hfac)(3)(IM6Me2py)], [Dy(hfac)(3)(IM4Me2py)] and [Dy(hfac)(3)(IM-5Me2py)] demonstrated that they are rigidly eight-coordinated with one IMnMe2py and three hfac ligands. Magnetic susceptibility measurements of the Gd(III) complexes indicate that the antiferromagnetic interaction between Gd(III) and imino nitroxide radical is different from the other lanthanide complexes containing nitronyl nitroxide radicals.

引用

页码：159 / 164

页数：6

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