Lead sulphide/phthalocyanine nanocomposite spun films

被引:5
|
作者
Nabok, AV [1 ]
Ray, AK
Cook, MJ
Burnham, PM
Iwantono
Yanuar, H
Simmonds, M
Basova, TV
机构
[1] Sheffield Hallam Univ, Nanotechnol Res Labs, Sch Engn, Sheffield S1 1WB, S Yorkshire, England
[2] Univ E Anglia, Wolfson Mat & Catalysis Ctr, Sch Chem Sci & Pharm, Norwich NR4 7TJ, Norfolk, England
[3] RAS, SB, Inst Inorgan Chem, Novosibirsk 630090, Russia
关键词
excitons; luminescence; nanoparticle; organic dyes; Raman spectra;
D O I
10.1109/TNANO.2004.834155
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Composite lead sulphide/phthalocyanine thin films were produced for the first time by exposure of thin spun films of a lipophilic lead phthalocyanine derivative to H2S gas. The formation of lead sulphide was confirmed by Raman and X-ray photoelectron spectroscopy measurements. UV-visible absorption and photoluminescence spectral measurements as well as a film morphology study using atomic force microscopy indicate the formation of lead sulphide clusters. From the blue spectral shift of the fundamental adsorption band, the size of the PbS clusters was estimated to be 2.24 nm.
引用
收藏
页码:388 / 394
页数:7
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