Mononuclear Nickel(II) Complexes with Schiff Base Ligands: Synthesis, Characterization, and Catalytic Activity in Norbornene Polymerization

被引：14
|
作者：
Xu, Yi-Mei [1 ]
Li, Kuan [1 ]
Wang, Yuhong [1 ]
Deng, Wei [1 ]
Yao, Zi-Jian [1 ]
机构：
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China
来源：
POLYMERS | 2017年 / 9卷 / 03期
基金：
上海市自然科学基金; 中国国家自然科学基金;
关键词：
Schiff base; X-ray crystals; catalysis; polymerization; nickel(II) complex; VINYL-TYPE POLYMERIZATION; CHAIN WALKING; ALPHA-OLEFINS; ETHYLENE; POLYMERS; COPOLYMERIZATION; POLYETHYLENE; MONOMERS; BEHAVIOR;
D O I：
10.3390/polym9030105
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The nickel(II) catalyst has manifested higher catalytic activity compared to that of other late transition metal catalysts for norbornene polymerization. Therefore, several structurally similar trans-nickel(II) compounds of N, O-chelate bidentate ligands were synthesized and characterized. Both the electronic effect and the steric hindrance influence polymerization. The molecular structures of 2, 4 and 5 were further confirmed by single-crystal X-ray diffraction.
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页数：10
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