Mononuclear Nickel(II) Complexes with Schiff Base Ligands: Synthesis, Characterization, and Catalytic Activity in Norbornene Polymerization

被引：14

作者：

Xu, Yi-Mei ^{[1
]}

Li, Kuan ^{[1
]}

Wang, Yuhong ^{[1
]}

Deng, Wei ^{[1
]}

Yao, Zi-Jian ^{[1
]}

机构：

[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China

来源：

POLYMERS | 2017年 / 9卷 / 03期

基金：

中国国家自然科学基金; 上海市自然科学基金;

关键词：

Schiff base; X-ray crystals; catalysis; polymerization; nickel(II) complex; VINYL-TYPE POLYMERIZATION; CHAIN WALKING; ALPHA-OLEFINS; ETHYLENE; POLYMERS; COPOLYMERIZATION; POLYETHYLENE; MONOMERS; BEHAVIOR;

D O I：

10.3390/polym9030105

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The nickel(II) catalyst has manifested higher catalytic activity compared to that of other late transition metal catalysts for norbornene polymerization. Therefore, several structurally similar trans-nickel(II) compounds of N, O-chelate bidentate ligands were synthesized and characterized. Both the electronic effect and the steric hindrance influence polymerization. The molecular structures of 2, 4 and 5 were further confirmed by single-crystal X-ray diffraction.

引用

页数：10

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