A new dirhodium(II) carboxamidate complex as a chiral lewis acid catalyst for enantioselective hetero-Diels-Alder reactions

被引：92
|
作者：
Anada, M
Washio, T
Shimada, N
Kitagaki, S
Nakajima, M
Shiro, M
Hashimoto, S [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan
[2] Rigaku Corp, Akishima, Tokyo 1968666, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 20期
关键词：
aldehydes; asymmetric catalysis; cycloaddition; heterocycles; rhodium;
D O I：
10.1002/anie.200453821
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Excellent enantioselectivities (up to 99% ee) and turnover numbers (up to 48000) were attained in the hetero-Diels-Alder reaction of a diverse range of aldehydes and activated dienes catalyzed by [Rh2(S-bptpi) 4] (see scheme).
引用
收藏
页码：2665 / 2668
页数：4
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