Supersilyl as an effective monodentate ligand to stabilize four-coordinate manganese(II) complexes

被引：4
|
作者：
Arata, Shogo [1 ]
Suzuki, Kosuke [2 ]
Yamaguchi, Kazuya [2 ]
Sunada, Yusuke [1 ,3 ]
机构：
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Meguro Ku, 4-6-1 Komaba, Tokyo 1538505, Japan
[2] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan
[3] Univ Tokyo, Inst Ind Sci, Meguro Ku, 4-6-1 Komaba, Tokyo 1538505, Japan
来源：
DALTON TRANSACTIONS | 2020年 / 49卷 / 48期
关键词：
UNSATURATED TRIS(TRIMETHYLSILYL)SILYL COMPLEXES; RAY CRYSTAL-STRUCTURES; SILYL HYDRIDE; POLYSILANE DERIVATIVES; MOLECULAR-STRUCTURES; TRANSITION-METALS; REACTION PATHWAYS; BOND METATHESIS; MAIN-GROUP; HYDROSILYLATION;
D O I：
10.1039/d0dt03837g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Supersilyl, -Si(SiMe3)(3), serves as an effective ligand to afford a series of four-coordinate manganese(II) complexes. A dinuclear complex, [(THF)Mn{Si(SiMe3)(3)}(mu-Br)](2) (2), was readily synthesized by the reaction of MnBr2 with KSi(SiMe3)(3). A subsequent ligand exchange of Br in 2 to -(OBu)-Bu-t, methyl, or hydride afforded the corresponding manganese(II) complexes.
引用
收藏
页码：17537 / 17541
页数：5
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