Supersilyl as an effective monodentate ligand to stabilize four-coordinate manganese(II) complexes

被引：4

作者：

Arata, Shogo ^{[1
]}

Suzuki, Kosuke ^{[2
]}

Yamaguchi, Kazuya ^{[2
]}

Sunada, Yusuke ^{[1
,3
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Meguro Ku, 4-6-1 Komaba, Tokyo 1538505, Japan

[2] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan

[3] Univ Tokyo, Inst Ind Sci, Meguro Ku, 4-6-1 Komaba, Tokyo 1538505, Japan

来源：

DALTON TRANSACTIONS | 2020年 / 49卷 / 48期

关键词：

UNSATURATED TRIS(TRIMETHYLSILYL)SILYL COMPLEXES; RAY CRYSTAL-STRUCTURES; SILYL HYDRIDE; POLYSILANE DERIVATIVES; MOLECULAR-STRUCTURES; TRANSITION-METALS; REACTION PATHWAYS; BOND METATHESIS; MAIN-GROUP; HYDROSILYLATION;

D O I：

10.1039/d0dt03837g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Supersilyl, -Si(SiMe3)(3), serves as an effective ligand to afford a series of four-coordinate manganese(II) complexes. A dinuclear complex, [(THF)Mn{Si(SiMe3)(3)}(mu-Br)](2) (2), was readily synthesized by the reaction of MnBr2 with KSi(SiMe3)(3). A subsequent ligand exchange of Br in 2 to -(OBu)-Bu-t, methyl, or hydride afforded the corresponding manganese(II) complexes.

引用

页码：17537 / 17541

页数：5

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