Cycling behavior of poly(vinylidene fluoride-hexafluoro propylene) (PVdF-HFP) membranes prepared by phase inversion method
被引:36
|
作者:
Stephan, AM
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机构:
Cent Electrochem Res Inst, Adv Batteries Div, Karaikkudi 630006, Tamil Nadu, IndiaCent Electrochem Res Inst, Adv Batteries Div, Karaikkudi 630006, Tamil Nadu, India
Stephan, AM
[1
]
Renganathan, NG
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机构:Cent Electrochem Res Inst, Adv Batteries Div, Karaikkudi 630006, Tamil Nadu, India
Renganathan, NG
Gopukumar, S
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机构:Cent Electrochem Res Inst, Adv Batteries Div, Karaikkudi 630006, Tamil Nadu, India
Gopukumar, S
Dale-Teeters
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机构:Cent Electrochem Res Inst, Adv Batteries Div, Karaikkudi 630006, Tamil Nadu, India
Dale-Teeters
机构:
[1] Cent Electrochem Res Inst, Adv Batteries Div, Karaikkudi 630006, Tamil Nadu, India
phase inversion;
non-solvent;
scanning electron microscopy;
BET surface area;
charge-discharge studies;
D O I:
10.1016/j.matchemphys.2003.11.038
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
A novel highly porous poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) membrane was prepared by phase inversion method with 1-butanol or methanol as non-solvent. These films where characterized by ionic conductivity, SEM and nitrogen adsorption/desorption analysis. The prepared membranes were employed as separator in LiA1(0.01) Co0.99O2/Li cells and their charge-discharge performances are presented. Although, these membranes vary slightly in the physical properties like, morphology and surface area no discernible changes could be seen in charge-discharge studies. (C) 2004 Elsevier B.V. All rights reserved.