Frontier of asymmetric epoxidation: Utilization of aqueous hydrogen peroxide

被引:2
|
作者
Matsumoto, Kazuhiro
机构
关键词
D O I
10.5059/yukigoseikyokaishi.64.869
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Optically active epoxides are versatile synthetic intermediates and asymmetric epoxidation is the most powerful method for their synthesis. Aqueous hydrogen peroxide is clean and atom-efficient and the epoxidation with it has been extensively studied. Thus, rapid advancement of asymmetric epoxidation using hydrogen peroxide has been made in recent years. In this Review de Debut, representative works of asymmetric epoxidation with aqueous hydrogen peroxide including a recent progress are overviewed.
引用
收藏
页码:869 / 870
页数:2
相关论文
共 50 条
  • [31] Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
    Wang, Chuan
    Yamamoto, Hisashi
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (04) : 1222 - 1225
  • [32] Iron-catalyzed asymmetric epoxidation of aromatic alkenes using hydrogen peroxide
    Gelalcha, Feyissa Gadissa
    Bitterlich, Bianca
    Anilkumar, Gopinathan
    Tse, Man Kin
    Beller, Matthias
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) : 7293 - 7296
  • [33] Mass-spectrometric and kinetic studies on the mechanism and degradation pathways of titanium salalen catalysts for asymmetric epoxidation with aqueous hydrogen peroxide
    Berkessel, Albrecht
    Brandenburg, Marc
    Schaefer, Mathias
    ADVANCED SYNTHESIS & CATALYSIS, 2008, 350 (09) : 1287 - 1294
  • [34] A practical and versatile access to dihydrosalen (Salalen) ligands:: Highly enantioselective titanium in situ catalysts for asymmetric epoxidation with aqueous hydrogen peroxide
    Berkessel, Albrecht
    Brandenburg, Marc
    Leitterstorf, Eva
    Frey, Julia
    Lex, Johann
    Schaefer, Mathias
    ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (14-15) : 2385 - 2391
  • [35] Kinetics of epoxidation of crotonic acid by aqueous hydrogen peroxide catalysed by sodium orthovanadate
    Agrawal, GL
    Singh, JV
    OXIDATION COMMUNICATIONS, 2002, 25 (01): : 82 - 86
  • [36] Epoxidation of cottonseed oil by catalysed by liquid aqueous hydrogen peroxide inorganic acids
    Dinda, Srikanta
    Patwardhan, Anand V.
    Goud, Valbhav V.
    Pradhan, Narayan C.
    BIORESOURCE TECHNOLOGY, 2008, 99 (09) : 3737 - 3744
  • [37] Titanium Salalen Catalysts for the Asymmetric Epoxidation of Terminal (and Other Unactivated) Olefins with Hydrogen Peroxide
    Berkessel, Albrecht
    ALDRICHIMICA ACTA, 2019, 52 (01) : 23 - 31
  • [38] ASYMMETRIC EPOXIDATION OF α,β-UNSATURATED KETONES WITH HYDROGEN PEROXIDE CATALYZED BY AXIALLY CHIRAL GUANIDINE BASE
    Terada, Masahiro
    Nakano, Megumi
    HETEROCYCLES, 2008, 76 (02) : 1049 - 1055
  • [39] Asymmetric epoxidation of N-enoylsultams with urea-hydrogen peroxide/trifluoroacetic anhydride
    Zhang, SJ
    Chan, WH
    Lee, AWM
    Wong, WY
    Rogatchov, VO
    Metz, P
    JOURNAL OF CHEMICAL RESEARCH-S, 2005, (12): : 755 - 756
  • [40] Biomimetic iron-catalyzed asymmetric epoxidation of aromatic alkenes by using hydrogen peroxide
    Gelalcha, Feyissa Gadissa
    Anilkumar, Gopinathan
    Tse, Man Kin
    Brueckner, Angelika
    Beller, Matthias
    CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (25) : 7687 - 7698