Fabrication of patterned organic thin film by low-energy electron beam lithography and surface-initiated ring-opening metathesis polymerization

被引:2
|
作者
Ding, Zhebo [1 ]
Ganem, Bruce [1 ]
机构
[1] Cornell Univ, Dept Chem & Biol Chem, Baker Lab, Ithaca, NY 14853 USA
关键词
patterned thin film; e-beam lithography; ring-opening metathesis polymerization; polymer brushes;
D O I
10.1139/V06-089
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High densities of immobilized polymer brushes have been created on solid supports in a spatially addressable fashion. Octadecyltrichlorosilane was self-assembled on a silicon substrate to form an inert monolayer. The substrate was then patterned by low-energy electron beam lithography. Finally, the exposed region was back-filled with a second functionalized silane and the pattern was further amplified by surface-initiated ring-opening metathesis polymerization. The patterned substrate was imaged by scanning electron microscopy and atomic force microscopy.
引用
收藏
页码:1254 / 1258
页数:5
相关论文
共 50 条
  • [41] Surface grafting of electrochemically crosslinked poly(3,4-ethylenedioxythiophene) (PEDOT) brushes via surface-initiated ring-opening metathesis polymerization
    Yavuz, Mustafa S.
    Sotzing, Gregory A.
    EUROPEAN POLYMER JOURNAL, 2012, 48 (04) : 875 - 880
  • [42] Surface-Initiated Ring-Opening Polymerization of L-lactide onto Hydroxy Terminated Surface Templates
    Haensch, Claudia
    Ott, Christina
    Hoeppener, Stephanie
    Schubert, Ulrich S.
    CURRENT NANOSCIENCE, 2010, 6 (02) : 124 - 130
  • [43] Grafting of poly(ε-caprolactone) on electrospun gelatin nanofiber through surface-initiated ring-opening polymerization
    Basaran, Ihsan
    Oral, Ayhan
    INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS AND POLYMERIC BIOMATERIALS, 2018, 67 (18) : 1051 - 1058
  • [44] Surface-initiated ring-opening metathesis polymerization (SI-ROMP) to attach a tethered organic corona onto CdSe/ZnS core/shell quantum dots
    Vatansever, Fatma
    Hamblin, Michael R.
    JOURNAL OF NANOPARTICLE RESEARCH, 2016, 18 (10)
  • [45] Surface-initiated ring-opening metathesis polymerization (SI-ROMP) to attach a tethered organic corona onto CdSe/ZnS core/shell quantum dots
    Fatma Vatansever
    Michael R. Hamblin
    Journal of Nanoparticle Research, 2016, 18
  • [46] Surface-Initiated Ring-Opening Metathesis Polymerization (SI-ROMP) Synthesis and Electropolymerization of Terthiophene-Functionalized Olefin Peripheral Dendrons
    Jiang, Guoqian
    Ponnapati, Ramakrishna
    Pernites, Roderick
    Felipe, Mary Jane
    Advincula, Rigoberto
    MACROMOLECULES, 2010, 43 (24) : 10262 - 10274
  • [47] CdSe-polymer composites prepared by surface initiated ring-opening metathesis polymerization.
    Skaff, H
    Ilker, F
    Coughlin, EB
    Emrick, T
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : D19 - D19
  • [48] Surface-Initiated Ring-Opening Metathesis Polymerization: A Method for Synthesizing Polymer-Functionalized Nanoparticles Exhibiting Semicrystalline Properties and Diverse Macromolecular Architectures
    LaNasa, Jacob A.
    Hickey, Robert J.
    MACROMOLECULES, 2020, 53 (19) : 8216 - 8232
  • [49] Surface-initiated ring-opening polymerization from cellulose model surfaces monitored by a Quartz Crystal Microbalance
    Carlsson, Linn
    Utsel, Simon
    Wagberg, Lars
    Malmstrom, Eva
    Carlmark, Anna
    SOFT MATTER, 2012, 8 (02) : 512 - 517
  • [50] Surface-initiated, ring-opening polymerization of p-dioxanone from gold and silicon oxide surfaces
    Yoon, KR
    Chi, YS
    Lee, KB
    Lee, JK
    Kim, DJ
    Koh, YJ
    Joo, SW
    Yun, WS
    Choi, IS
    JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (12) : 2910 - 2914