Synthesis of fluorinated imines and carbodiimides from azides via aza-Wittig reaction

被引：4
|
作者：
Wu, Yongming
Sun, Qingrui
Deng, Juan
Tian, Weisheng
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
[2] SHanghai Normal Univ, Life & Environm Sci Coll, Shanghai 200234, Peoples R China
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2006年 / 127卷 / 09期
基金：
中国国家自然科学基金;
关键词：
fluoroalkylazide; N-fluoroalkylimines; N-fluoroalkyliminophosphoranes; N; N '-difluoroalkylated carbodiimides; Staudinger reaction; aza-Wittig reaction;
D O I：
10.1016/j.jfluchem.2006.06.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Staudinger reaction of fluoroalkylazides were studied. A series of N-fluoroalkylimines were synthesized via aza-Wittig reaction of N-fluoroalkyliminophosphoranes. The N,N'-difluoroalkylated carbodiimide was also synthesized via the reaction of N-fluoroalkyliminophosphoranes with carbon dioxide or carbon disulfide. (c) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：1152 / 1157
页数：6
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