Cu(OAc)2-Catalyzed Aerobic Oxidative Dehydrogenation Coupling: Synthesis of Heptacyclic Quinolizino[3,4,5,6-kla]perimidines

被引：39

作者：

Feng, Bin-Bin ^{[1
]}

Liu, Jian-Quan ^{[1
]}

Wang, Xiang-Shan ^{[1
]}

机构：

[1] Jiangsu Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Green Synth Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 03期

关键词：

BOND FORMATION; DERIVATIVES; ARYLATION; CYCLIZATION; ACTIVATION; THIOPHENES; CLEAVAGE; RHODIUM; ARENES;

D O I：

10.1021/acs.joc.6b02644

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Cu(OAc)(2)-catalyzed domino tricyclization between naphthalene-1,8-diamine and 2-(phenylethynyl)-benzaldehyde is described, enabling aerobic oxidative dehydrogenation coupling to access heptacyclic quinolizino[3,4,5,6-kla]perimidines. In this reaction, the formation of three new rings and four new bonds was achieved in a functional-group-compatible fashion, allowing a facile method toward fused azaheterocycles containing both quinolizine and perimidine moieties.

引用

页码：1817 / 1822

页数：6

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