Fabrication of infinite two-dimensional sheets of tetragonal metal(II) lattices -: X-ray crystal structures and magnetic properties of [M(CA)(pyz)]n (M2+ = Mn2+ and Co2+; H2CA = chloranilic acid; pyz = pyrazine)

被引：26

作者：

Kumagai, H

Kawata, S

Kitagawa, S ^{[1
]}

机构：

[1] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

[2] Shizuoka Univ, Dept Chem, Shizuoka 4228529, Japan

[3] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

INORGANICA CHIMICA ACTA | 2002年 / 337卷

关键词：

cobalt (II); manganese (II); X-ray crystal structure; magnetic properties; chloranilic acid;

D O I：

10.1016/S0020-1693(02)01084-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New cobalt(II) and manganese(II) co-ordination polymers containing tetragonal lattices [M(CA)(pyz)](n) (M2+ = Mn2+ (1) and Co2+ (2); H(2)CA=chloranilic acid; pyz = pyrazine) have been synthesized and characterized. Both compounds 1 and 2 are isomorphous. Each metal atom for 1 and 2 displays a six-coordinate geometry with the two bis-chelating CA(2-) anions and pyz molecules, providing an infinite square grid sheet. The temperature dependence of magnetic susceptibilities revealed the presence of antiferromagnetic interaction with J=-0.32 cm(-1), zJ' = -0.34 cm(-1), g=2.00 for 1 and J = -1.09 cm(-1), J' = -0.55 cm(-1), g=2.27 for 2, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：387 / 392

页数：6

共 35 条

[21] Synthesis, X-ray structures and magnetic properties of linear chain 4-cyanopyridine compounds: [Cu(4-CNpy)(4)(H2O)](ClO4)(2) and M(4-CNpy)(2)Cl-2 (M=Mn, Fe, Co, Ni, Cu)
Zhang, WR
Jeitler, JR
Turnbull, MM
Landee, CP
Wei, MY
Willett, RD
INORGANICA CHIMICA ACTA, 1997, 256 (02) : 183 - 198
[22] ORGANOMETALLIC COMPLEXES WITH METAL-METAL BONDS .19. COMPARISON OF 2 STRATEGIES TOWARD THE SYNTHESES OF PLATINUM MIXED-METAL CLUSTERS - REACTIVITY OF LINEAR M-PT-M AND MN-PT-MN COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF PT2M2(ETA-5-C5H5)2(MU-3-CO)2(MU-CO)4(PET3)2 WITH M = CR, MO, AND W1
BENDER, R
BRAUNSTEIN, P
JUD, JM
DUSAUSOY, Y
INORGANIC CHEMISTRY, 1984, 23 (26) : 4489 - 4502
[23] Syntheses, X-ray crystal structures and catalytic activities of the manganese(II) butanedioic acid complexes [Mn2(O2C(CH2)2 CO2)2(phen)2(H2O)4]u2H2O and {[Mn(O2C(CH2)2CO2)(bipy) (H2O)2]uH2O}n
McCann, M.
Casey, M. T.
Devereux, M.
Curran, M.
Polyhedron, 16 (15):
[24] Functionalized metal oxide clusters:: Synthesis, characterization, crystal structures, and magnetic properties of a novel series of fully reduced heteropolyoxovanadium cationic clusters decorated with organic ligands -: [MVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6]X (M = Li, X = Cl•LiCl; M-Na,X-Cl•H2O; M = Mg, X=2Br•H2O; M Mn, Fe, X 2Cl; M = Co, Ni, X=2CI•H2O)
Khan, MI
Tabussum, S
Doedens, RJ
Golub, VO
O'Connor, CJ
INORGANIC CHEMISTRY, 2004, 43 (19) : 5850 - 5859
[25] Synthesis, crystal structures and magnetic properties of helical double-stranded three-dimensional network [Co(NO3)2(bpt)2•2CH3OH]n and two-dimensional network [Mn(NCS)2(bpt)3•H2O]n (bpt = N,N′-bis(3-pyridylmethyl)thiourea)
Li, G
Hou, HW
Niu, YY
Fan, YT
Liu, ZS
Ge, TZ
Xin, XQ
INORGANICA CHIMICA ACTA, 2002, 332 : 216 - 222
[26] DIMER SPECIES IN AQUEOUS-SOLUTIONS OF M-PHENYLENEDIAMINE-N,N,N',N'-TETRA-ACETIC ACID (M-H4PDTA) WITH COPPER(II) AND OF PYRIDINE-2,6-DIAMINE-N,N,N',N'-TETRA-ACETIC ACID (2,6-H4PYDTA) WITH NICKEL(II) - X-RAY CRYSTAL-STRUCTURES OF NA4[CU2(M-PDTA)2].18H2O, NA4[CO2(M-PDTA)2].10H2O, AND NA4[NI2(2,6-PYDTA)2].8H2O
MEDEROS, A
GILI, P
DOMINGUEZ, S
BENITEZ, A
PALACIOS, MS
HERNANDEZPADILLA, M
MARTINZARZA, P
RODRIGUEZ, ML
RUIZPEREZ, C
LAHOZ, FJ
ORO, LA
BRITO, F
ARRIETA, JM
VLASSI, M
GERMAIN, G
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (04): : 1477 - 1491
[27] Two-dimensional rhombohedral grid coordination polymers [M(bbbt)2(NCS)2]n (M=Co, Mn, or Cd; bbbt=1,1′-(1,4-butanediyl) bis-1H-benzotriazole):: Synthesis, crystal structures, and third-order nonlinear optical properties
Hou, HW
Meng, XR
Song, YL
Fan, YT
Zhu, Y
Lu, HJ
Du, CX
Shao, WH
INORGANIC CHEMISTRY, 2002, 41 (15) : 4068 - 4075
[28] CHEMISTRY OF ORTHO-XYLIDINE METAL-COMPLEXES .2. PREPARATION AND PROPERTIES OF THE ORTHO-XYLIDINE, METAL(IV) COMPLEXES - [M(CH2C6H4CH2-O) (ETA-C5H4R)2] (M = TI, ZR, HF, OR NB, R = H OR SIME3) AND [(M'(CH2C6H4CH2-O)2(OC4H8))N] (M' = TI, ZR, OR HF) - X-RAY CRYSTAL-STRUCTURES OF THE METALLAINDANES [M(CH2C6H4CH2-O)-(ETA-C5H4R)2] (R = H, M = TI, ZR, OR HF, R = SIME3, M = NB)CH
BRISTOW, GS
LAPPERT, MF
MARTIN, TR
ATWOOD, JL
HUNTER, WF
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (03): : 399 - 413
[29] THE HETERONUCLEAR CLUSTER CHEMISTRY OF THE GROUP 1B METALS .3. SYNTHESIS, STRUCTURES, AND CHEMICAL-PROPERTIES OF THE TRIMETALLIC HEXANUCLEAR GROUP 1B METAL CLUSTER COMPOUNDS [MM'RU4(MU-3-H)2(CO)12(PPH3)2] (M = CU, M' =AG OR AU, M =AG, M' =AU) - X-RAY CRYSTAL-STRUCTURE OF THE COMPLEX [AGCURU4(MU-3-H)2(CO)12(PPH3)2].CH2CL2E
FREEMAN, MJ
ORPEN, AG
SALTER, ID
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (05): : 1001 - 1008
[30] THE HETERONUCLEAR CLUSTER CHEMISTRY OF THE GROUP 1B METALS .6. SYNTHESIS, STRUCTURES, AND DYNAMIC BEHAVIOR OF THE BIMETALLIC HEXANUCLEAR GROUP-1B METAL CLUSTER COMPOUNDS [M2RU4(MU-3-H)2(MU-PH2P(CH2)NPPH2)(CO)12] (M=CU OR AG,N=1-6) - X-RAY CRYSTAL-STRUCTURES OF [CU2RU4(MU-3-H)2-(MU-PH2P(CH2)NPPH2)(CO)12](N = 2, 3, OR 5)
BROWN, SSD
SALTER, ID
TOUPET, L
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (03): : 757 - 767

← 1 2 3 4 →