Fabrication of infinite two-dimensional sheets of tetragonal metal(II) lattices -: X-ray crystal structures and magnetic properties of [M(CA)(pyz)]n (M2+ = Mn2+ and Co2+; H2CA = chloranilic acid; pyz = pyrazine)

被引：26
|
作者：
Kumagai, H
Kawata, S
Kitagawa, S [1 ]
机构：
[1] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[2] Shizuoka Univ, Dept Chem, Shizuoka 4228529, Japan
[3] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan
来源：
INORGANICA CHIMICA ACTA | 2002年 / 337卷
关键词：
cobalt (II); manganese (II); X-ray crystal structure; magnetic properties; chloranilic acid;
D O I：
10.1016/S0020-1693(02)01084-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New cobalt(II) and manganese(II) co-ordination polymers containing tetragonal lattices [M(CA)(pyz)](n) (M2+ = Mn2+ (1) and Co2+ (2); H(2)CA=chloranilic acid; pyz = pyrazine) have been synthesized and characterized. Both compounds 1 and 2 are isomorphous. Each metal atom for 1 and 2 displays a six-coordinate geometry with the two bis-chelating CA(2-) anions and pyz molecules, providing an infinite square grid sheet. The temperature dependence of magnetic susceptibilities revealed the presence of antiferromagnetic interaction with J=-0.32 cm(-1), zJ' = -0.34 cm(-1), g=2.00 for 1 and J = -1.09 cm(-1), J' = -0.55 cm(-1), g=2.27 for 2, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：387 / 392
页数：6
相关论文
共 35 条
  • [1] Synthesis, structure and magnetic properties of a two-dimensional nickel(II) coordination polymer, {[Ni(pzdc)(pyz)]&middot2H2O}n (H2pzdc = pyrazine-2,3-dicarboxylic acid; pyz = pyrazine)
    Okubo, Takashi
    Kondo, Mitsuru
    Kawata, Satoshi
    Kitagawa, Susumu
    Miyazaki, Akira
    Enoki, Toshiaki
    Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 1996, 285-286 : 115 - 120
  • [2] Crystal structure and magnetic property of cobalt(II) assembled compound, {[Co(CA)(bipym)](H2O)2}n (H2CA = chloranilic acid, bipym=2,2′-bipyrimidine)
    Kabir, MK
    Kawata, S
    Adachi, K
    Kumagai, H
    Kitagawa, S
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 342 : 211 - 216
  • [3] Synthesis, structure and magnetic properties of a two-dimensional nickel(II) coordination polymer, {[Ni(pzdc)(pyz)]center dot 2H(2)O}(n) (H(2)pzdc equals pyrazine-2,3-dicarboxylic acid; pyz equals pyrazine)
    Okubo, T
    Kondo, M
    Kawata, S
    Kitagawa, S
    Miyazaki, A
    Enoki, T
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1996, 285 : 437 - 442
  • [4] Module-based assembly of copper(II) chloranilate compounds:: Syntheses, crystal structures, and magnetic properties of {[Cu2(CA)(terpy)2][Cu(CA)2]}n and (Cu2(CA)(terpy)2(dmso)2][Cu(CA)2(dmso)2](EtOH)}n (H2CA = chloranilic acid, terpy = 2,2′:6′,2"-terpyridine, dmso = dimethyl sulfoxide)
    Kawahara, M
    Kabir, K
    Yamada, K
    Adachi, K
    Kumagai, H
    Narumi, Y
    Kindo, K
    Kitagawa, S
    Kawata, S
    INORGANIC CHEMISTRY, 2004, 43 (01) : 92 - 100
  • [5] High-dimensional malonate-based materials:: Synthesis, crystal structures and magnetic properties of [M2(mal)2(L)(H2O)2]n•n(H2O) M = Zn(II), Co(II); H2mal = malonic acid, L = pyrimidine, pyrazine
    Delgado, FS
    Sanchiz, J
    Ruiz-Pèrez, C
    Lloret, F
    Julve, M
    CRYSTENGCOMM, 2003, 5 : 280 - 284
  • [6] 2-DIMENSIONAL SHEETS OF TETRAGONAL COPPER(II) LATTICES - X-RAY CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [CU(C6O4CL2)(C4H4N2)](N)
    KAWATA, S
    KITAGAWA, S
    KONDO, M
    FURUCHI, I
    MUNAKATA, M
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (17): : 1759 - 1761
  • [7] COORDINATION-COMPLEXES WITH INFINITE LATTICE STRUCTURES - SOLVOTHERMAL SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF K(2)M[NC5H3(CO2)(2)-2,3](2) (M=MN, ZN)
    GUTSCHKE, SOH
    SLAWIN, AMZ
    WOOD, PT
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (21) : 2197 - 2198
  • [8] Two-dimensional metal dicyanamide frameworks of BeTriMe[M(dca)3(H2O)] (BeTriMe = benzyltrimethylammonium; dca = dicyanamide; M = Mn2+, Co2+, Ni2+): coexistence of polar and magnetic orders and nonlinear optical threshold temperature sensing
    Maczka, Miroslaw
    Gagor, Anna
    Stroppa, Alessandro
    Goncalves, Joao Nuno
    Zareba, Jan K.
    Stefanska, Dagmara
    Pikul, Adam
    Drozd, Marek
    Sieradzki, Adam
    JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (34) : 11735 - 11747
  • [9] Synthesis and X-ray powder diffraction data of transition metal derivatives of maleic acid.: I.: M2+ (C4H3O4-)2•4H2O (M2+=Mn, Fe, Co, Ni, and Zn)
    Briceño, A
    González, T
    de Delgado, GD
    Guevara, R
    Delgado, JM
    POWDER DIFFRACTION, 2002, 17 (02) : 139 - 143
  • [10] Crystal Growth, Structural Characterization, and Magnetic Properties of New Uranium(IV) Containing Mixed Metal Oxalates: Na2U2M(C2O4)6(H2O)4 (M = Mn2+, Fe2+, Co2+, and Zn2+)
    Yeon, Jeongho
    Smith, Mark D.
    Sefat, Athena S.
    zur Loye, Hans-Conrad
    INORGANIC CHEMISTRY, 2013, 52 (04) : 2199 - 2207
1234