Flexible biodegradable transparent heaters based on fractal-like leaf skeletons

We present a facile method to prepare flexible, transparent, biodegradable, and fast resistive heaters by applying silver (Ag) nanowires onto fractal-like leaf skeletons. The fractal-like structure of the leaf skeleton maximizes its surface area, improving the transfer of heat to its surroundings and thus making the heater fast, without compromising transparency. Ag ion layer on the leaf skeleton helps to conformally cover the surface with Ag nanowires. The sheet resistance of the heater can be controlled by the loading of Ag nanowires, without sacrificing the optical transmittance (similar to 80% at 8 Omega sq(-1)). The heating is uniform and the surface temperature of a 60mmx60mm heater (8 Omega sq(-1)) can quickly (5-10s) raise to 125 degrees C with a low voltage (6V). The heater displays excellent mechanical flexibility, showing no significant change in resistance and heating temperature when bent up to curvature of 800m(-1). Finally, we demonstrate the potential of the bioinspired heater as a thermotherapy patch by encapsulating it in a biodegradable tape and mounting it on the human wrist and elbow. This study shows that fractal-like structures from nature can be repurposed as fractal designs for flexible electronics.