Synthesis and Characterization of a New 2D Ca(II) Coordination Polymer Containing 1D Calcium-oxygen Chains

被引：0
|
作者：
Wang Ji-Jiang [1 ]
Tang Long [1 ]
Hou Xiang-Yang [1 ]
Gao Lou-Jun [1 ]
Fu Feng [1 ]
Zhang Mei-Li [1 ]
机构：
[1] Yanan Univ, Dept Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 07期
基金：
中国国家自然科学基金;
关键词：
coordination polymer; calcium-oxygen chains; photoluminescent property; LUMINESCENT; PROPERTY;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 2D Ca(II) coordination polymer, [Ca(H(2)btc)(H2O)(2)](n) (1, H(4)btc = biphenyl-3,3',5,5'-tetracarboxylic acid), has been synthesized using the hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analysis, IR, thermogravimetric analysis, and photoluminescent analysis. Complex 1 crystallizes in the monoclinic system, space group C2/c with a = 17.5676(15), b = 11.4496(8), c = 7.6197(8) angstrom, beta = 102.787(2)degrees, V = 1494.6(2) angstrom(3), Z = 4, D-c= 1.797 Mg.m(-3), mu = 0.483 mm(-1), F(000) = 832, the final R = 0.0348 and wR = 0.0915 for 1521 observed reflections with I > 2 sigma(I). Complex 1 has a 2D network containing 1D calcium-oxygen chains. These 2D networks are further connected by O-H center dot center dot center dot O hydrogen bonding interactions to generate a 3D supramolecular structure.
引用
收藏
页码：1069 / 1073
页数：5
相关论文
共 50 条
  • [21] Synthesis, Crystal Structure and Properties of a Chiral 2D Zn(II) Coordination Polymer with Helical Chains
    Kang, Ting-Ting
    Tang, Hao
    Wei, Yong-Li
    Zang, Shuang-Quan
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (04): : 403 - 407
  • [22] Gallium Coordination Polymers Based on Bis-pyridylethylene Containing Neutral and Cationic 1D Chains and 2D Networks
    Schaefer, Thomas
    Mueller-Buschbaum, Klaus
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2018, 644 (24): : 1791 - 1795
  • [23] New 1D and 2D gels for the characterization of hydrophobic proteins
    Tokarski, C.
    Fillet, M.
    Rolando, C.
    MOLECULAR & CELLULAR PROTEOMICS, 2006, 5 (10) : S141 - S141
  • [24] Synthesis, Crystal Structure and Properties of 1D Manganese(II) Coordination Polymer
    Fang Xiang-Qian
    Chen Peng-Gang
    Zhu Zhi-Biao
    Deng Zhao-Peng
    Gao Shan
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (09) : 1733 - 1737
  • [25] Hydrothermal Synthesis, Characterization and Gas Adsorption Study of a Zn(II) Based 1D Coordination Polymer
    Sanda, Suresh
    Jena, Himanshu Sekhar
    Parshamoni, Srinivasulu
    Konar, Sanjit
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES INDIA SECTION A-PHYSICAL SCIENCES, 2014, 84 (02) : 213 - 219
  • [26] Synthesis and Structural Characterization of a New 2D Coordination Polymer [Cu(pzta)2]n
    Hu Xin
    Liu Cong
    Wang Yongjiang
    Guo Jixi
    CHINESE JOURNAL OF CHEMISTRY, 2009, 27 (03) : 479 - 482
  • [27] Hydrothermal Synthesis, Characterization and Gas Adsorption Study of a Zn(II) Based 1D Coordination Polymer
    Suresh Sanda
    Himanshu Sekhar Jena
    Srinivasulu Parshamoni
    Sanjit Konar
    Proceedings of the National Academy of Sciences, India Section A: Physical Sciences, 2014, 84 : 213 - 219
  • [28] Synthesis and characterization of 1D coordination polymer of tin and 4-aminothiophenol
    Burkett, Eon S.
    Siddiquee, Tasneem A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [29] Ligand replacement on 1D and 2D coordination polymers
    Johnson, Bret
    Johnson, Mike
    Beattie, Nicholas
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [30] A New Heterometallic Pb(II)-Ca(II) Coordination Polymer with 2D Pb-O-Ca Inorganic Connectivity
    An, Z.
    Gao, J.
    Wang, J.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2018, 44 (12) : 818 - 823
12345