Enantioselective radical addition reactions to imines using binaphthol-derived chiral N-triflyl phosphoramides

被引：43
|
作者：
Lee, Sunggi [1 ]
Kim, Sunggak [1 ]
机构：
[1] Korea Adv Inst Sci & Technol, Sch Mol Sci BK 21, Dept Chem, Taejon 305701, South Korea
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 26期
关键词：
Radical; Chiral Bronsted acid; Imine; Asymmetric; Catalytic; BRONSTED ACID CATALYST; TRANSFER HYDROGENATION; ALKYLATION; INDOLES;
D O I：
10.1016/j.tetlet.2009.02.136
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Binaphthol-derived chiral phosphoric acid catalysts were applied to enantioselective radical addition reactions of imines and provided chiral amines with good enantioselectivities (73-84% ee). Furthermore,, the enantioselectivities were not affected by either electronic properties of phenyl imines or radical precursors. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3345 / 3348
页数：4
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