Na2Co(H2PO4)4•4H2O

被引:0
|
作者
Guesmi, A [1 ]
Zid, MF [1 ]
Driss, A [1 ]
机构
[1] Fac Sci Tunis, Dept Chim, Tunis 1060, Tunisia
关键词
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, disodium cobalt tetrakis(dihydrogenphosphate) tetrahydrate, the Co-II ion lies on an inversion centre and is octahedrally surrounded by two water molecules and four H2PO4 groups to give a cobalt complex anion of the form [Co(H2PO4)(4)(OH2)](2-). The three-dimensional framework results from hydrogen bonding between the anions. The relationship with the structures of Co(H2PO4)(2). 2H(2)O and K2CoP4O12. 5H(2)O is discussed.
引用
收藏
页码:511 / 512
页数:2
相关论文
共 50 条
  • [31] Hydrothermal synthesis and crystal structure of a new polyoxometalate (CH3CH2)4N]4H3O{ Na[(HMo2O5)3(HPO4) (H2PO4)3]2} • (H2PO4)2 • 10H2O
    Zhang, H
    Xu, L
    Wang, EB
    Hu, CW
    Chen, JT
    Yao, YG
    Qin, YY
    [J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (06): : 1010 - 1012
  • [32] Manganoblodite, Na2Mn(SO4)2•4H2O, and cobaltoblodite, Na2Co(SO4)2•4H2O: two new members of the blodite group from the Blue Lizard mine, San Juan County, Utah, USA
    Kasatkin, A. V.
    Nestola, F.
    Plasil, J.
    Marty, J.
    Belakovskiy, D. I.
    Agakhanov, A. A.
    Mills, S. J.
    Pedron, D.
    Lanza, A.
    Favaro, M.
    Bianchin, S.
    Lykova, I. S.
    Golias, V.
    Birch, W. D.
    [J]. MINERALOGICAL MAGAZINE, 2013, 77 (03) : 367 - 383
  • [33] THE CRYSTAL-STRUCTURE OF CO(H2PO4)2.2H3PO4
    HERAK, R
    PRELESNIK, B
    CURIC, M
    DJURIC, S
    [J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1983, 164 (1-2): : 25 - 30
  • [34] Nabesite -: Na2BeSi4O10•4H2O
    不详
    [J]. CANADIAN MINERALOGIST, 2002, 40 : 1543 - 1543
  • [35] DEHYDRATIONS OF CA(H2PO4)2-H2O AND MG(H2PO4)2-2H2O AND THEIR REACTIONS WITH KCL, EXAMINED WITH SIMULTANEOUS TG, DTG, DTA AND EGA
    PYLDME, M
    TYNSUAADU, K
    PAULIK, F
    PAULIK, J
    ARNOLD, M
    [J]. JOURNAL OF THERMAL ANALYSIS, 1979, 17 (02): : 479 - 488
  • [36] THERMAL DEHYDRATION OF CA(H2PO4)2.H2O AND MG(H2PO4)2.2H2O AND THEIR MIXTURES WITH KCL AND SILICIC-ACID ADDITIONS
    PYLDME, ME
    PYLDME, YK
    TYNSUAADU, KO
    VEIDERMA, MA
    [J]. ZHURNAL NEORGANICHESKOI KHIMII, 1981, 26 (01): : 58 - 61
  • [37] Structure et proprietes magnetiques du compose NH4Fe3(H2PO4)6 (HPO 4)2,4H2O
    Mgaidi, A.
    Boughzala, H.
    Driss, A.
    Clerac, R.
    Coulon, C.
    [J]. Journal of Solid State Chemistry, 1999, 144 (01): : 163 - 168
  • [38] HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURES OF SR2V(PO4)2(H2PO4) AND SR2FE(PO4)2(H2PO4)
    LII, KH
    LEE, TC
    LIU, SN
    WANG, SL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (07): : 1051 - 1054
  • [39] Synthesis and structure of [Zn8(HPO4)8(H2PO4)8]•[(C2H8N)8]•4H2O
    Reinert, P
    Logar, NZ
    Patarin, J
    Kaucic, V
    [J]. EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1998, 35 (4-5): : 373 - 387
  • [40] Contribution to the study of the julienite [Na2Co(CSN)(4) 8H(2)O]
    Schoep, A
    Billiet, V
    [J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1935, 91 (3/4): : 229 - 234