Physicochemical Transformations During Low-Temperature Synthesis of Zirconium Carbide

被引：2

作者：

Shishkin, R. A. ^{[1
]}

Kudyakova, V. S. ^{[1
]}

Zhirenkina, N. V. ^{[1
]}

机构：

[1] Ural Fed Univ, Ekaterinburg, Russia

来源：

REFRACTORIES AND INDUSTRIAL CERAMICS | 2019年 / 60卷 / 01期

关键词：

joint reduction; magnesiothermy; zircon carbide ZrC; sodium carbonate Na2CO3; low-temperature synthesis; SOLID-STATE REACTION; SODIUM;

D O I：

10.1007/s11148-019-00317-x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Joint reduction of zirconium dioxide and sodium carbonate to form zirconium carbide was studied. Magnesiothermic reduction of ZrO2 was shown to occur at 600 - 620 degrees C; Na2CO3, 590 - 610 degrees C. Thermodynamic calculations and x-ray phase analyses indicated the transformations occurring during the synthesis and the resulting reaction products. Use of graphite as the carbon source did not lead to ZrC formation at 700 - 900 degrees C, in contrast with Na2CO3.

引用

页码：105 / 108

页数：4

共 50 条

[41] ZIRCONIUM OXIDATION AT LOW-TEMPERATURE AND PRESSURE - COMMENT
COX, B
JOURNAL OF NUCLEAR MATERIALS, 1995, 218 (02) : 261 - 264
[42] NMR LOW-TEMPERATURE STUDY OF ZIRCONIUM HYDRIDE
NASKIDASHVILI, IA
SHARIMANOV, YG
VYLKU, N
DEMKO, D
SIMALECHANU, V
FIZIKA TVERDOGO TELA, 1977, 19 (11): : 3465 - 3466
[43] Zirconium dissolution by low-temperature chlorination in dimethylformamide
Chekmarev, A. M.
Buchikhin, E. P.
Sidorov, D. S.
Koshcheev, A. M.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2007, 41 (05) : 752 - 754
[44] Zirconium dissolution by low-temperature chlorination in dimethylformamide
A. M. Chekmarev
E. P. Buchikhin
D. S. Sidorov
A. M. Koshcheev
Theoretical Foundations of Chemical Engineering, 2007, 41 : 752 - 754
[45] Low-temperature synthesis of boron carbide nanofibers via electrospinning to reinforce composites
Aslı Dörtler Kesici
Nadir Kiraz
Chemical Papers, 2021, 75 : 5839 - 5848
[46] Low-temperature synthesis of tantalum carbide by facile one-pot reaction
Jiang, Jinming
Wang, Song
Li, Wei
Chen, Zhaohui
CERAMICS INTERNATIONAL, 2016, 42 (06) : 7118 - 7124
[47] Low-temperature molten salt synthesis of high-entropy carbide nanopowders
Ning, Shanshan
Wen, Tongqi
Ye, Beilin
Chu, Yanhui
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2020, 103 (03) : 2244 - 2251
[48] Low-temperature synthesis of boron carbide nanofibers via electrospinning to reinforce composites
Dortler Kesici, Asli
Kiraz, Nadir
CHEMICAL PAPERS, 2021, 75 (11) : 5839 - 5848
[49] Carbide characterization in low-temperature tempered steels
Zhu, Chen
Cerezo, Alfred
Smith, George D. W.
ULTRAMICROSCOPY, 2009, 109 (05) : 545 - 552
[50] Low-temperature joining of boron carbide ceramics
Sekine, Kiyoto
Kumazawa, Takeshi
Tian, Wu-Bian
Hyuga, Hideki
Kita, Hideki
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2012, 120 (1401) : 207 - 210

← 1 2 3 4 5 →