Synthesis of (+)-(1S,2R) and (-)-(1R,2S)-2-aminocyclobutane-1-carboxylic acids

被引：23

作者：

Gauzy, C ^{[1
]}

Pereira, E ^{[1
]}

Faure, S ^{[1
]}

Aitken, DJ ^{[1
]}

机构：

[1] Univ Clermont Ferrand, Dept Chim, Lab SEESIB CNRS, F-63177 Clermont Ferrand, France

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 38期

关键词：

beta-amino acid; cyclobutane; stereoselective synthesis; 2+2] photocycloaddition reaction;

D O I：

10.1016/j.tetlet.2004.07.110

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(+)-(I S,2R) and (-)-(I R,2S)-2-aminocyclobutane-1-carboxylic acids have been prepared in >97% ee and in 33% and 20% overall yields starting from a single, chiral, bicyclic compound perceived as a chiral uracil equivalent. Construction of the cyclobutane ring is achieved via a [2+2] photocycloaddition reaction of this chiral precursor with ethylene. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：7095 / 7097

页数：3

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