Stable macrocyclic and tethered donor-acceptor systems. Intramolecular bipyridinium and tetrathiafulvalene assemblies

被引：56
|
作者：
Simonsen, KB
Zong, KW
Rogers, RD
Cava, MP
Becher, J
机构：
[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487
[2] ODENSE UNIV,DEPT CHEM,DK-5230 ODENSE M,DENMARK
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1997年 / 62卷 / 03期
关键词：
D O I：
10.1021/jo961782a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of compounds has been prepared in which a tetrathiafulvalene (TTF)-derived donor is covalently tethered or bridged to one or more bipyridinium (viologen) accepters. The relative degree of charge transfer observed in this series is discussed as a function of structure. The greatest CT effect is seen in the cyclophanes 9a-c and 13.
引用
收藏
页码：679 / 686
页数：8
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