Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air

被引：51
|
作者：
Zhao, Miao [1 ,2 ]
Yu, Zhengkun [1 ]
Yan, Shenggang [3 ]
Li, Yang [2 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
[2] Dalian Univ Technol, Coll Chem Engn, Dept Polymer Mat, Dalian 116012, Liaoning, Peoples R China
[3] Dalian Maritime Univ, Electromech & Mat Engn Coll, Dalian 116026, Liaoning, Peoples R China
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 32期
基金：
中国国家自然科学基金;
关键词：
ASYMMETRIC TRANSFER-HYDROGENATION; ENANTIOSELECTIVE TRANSFER HYDROGENATION; CHEMOSELECTIVE TRANSFER HYDROGENATION; TETHERED RUTHENIUM(II) CATALYST; PYRAZOLYL-IMIDAZOLYL LIGAND; AROMATIC KETONES; PNNP LIGAND; COMPLEXES; WATER; BEARING;
D O I：
10.1016/j.tetlet.2009.05.100
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transfer hydrogenation (TH) of ketones and aldehydes was efficiently carried out in 2-propanol at room temperature by means of a ruthenium(II) complex catalyst bearing a 2-(benzoimidazol-2-yl)-6-(pyrazol-1-yl)pyridine ligand. TH of the ketone substrates proceeded in air, reaching final TOFs of up to 59,400 h(-1), and the reduction of aldehydes proceeded under a nitrogen atmosphere to achieve final TOFs of up to 5940 h(-1). (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4624 / 4628
页数：5
相关论文
共 50 条
  • [41] Ru-η6-benzene-phosphine complex-catalyzed transfer hydrogenation of ketones
    Wang, Lei
    Yang, Qin
    Fu, Hai-Yan
    Chen, Hua
    Yuan, Mao-Lin
    Li, Rui-Xiang
    APPLIED ORGANOMETALLIC CHEMISTRY, 2011, 25 (08) : 626 - 631
  • [42] Remote dipole effects as a means to accelerate [Ru(amino alcohol)]-catalyzed transfer hydrogenation of ketones
    Nordin, SJM
    Roth, P
    Tarnai, T
    Alonso, DA
    Brandt, P
    Andersson, PG
    CHEMISTRY-A EUROPEAN JOURNAL, 2001, 7 (07) : 1431 - 1436
  • [43] Co(II)-Catalyzed Additive-Free Transfer Hydrogenation of N-Heteroarenes at Room Temperature
    Mahapatra, Divya
    Sau, Anirban
    Ghosh, Tanmoy
    Roy, Arkamitra
    Kundu, Sabuj
    ORGANIC LETTERS, 2024, 26 (28) : 6001 - 6005
  • [44] Asymmetric transfer hydrogenation of ketones catalyzed by chiral macrocyclic cobalt(II) complexes
    Ruan, Sun-Hong
    Fan, Zi-Wei
    Zhang, Wen-Jing
    Xu, Han
    An, Dong -Li
    Wei, Zan-Bin
    Yuan, Ru-Ming
    Gao, Jing-Xing
    Li, Yan-Yun
    JOURNAL OF CATALYSIS, 2023, 418 : 100 - 109
  • [45] Transfer Hydrogenation of Ketones Catalyzed by 1-Alkylbenzimidazole Ruthenium(II) Complexes
    İsmail Özdemir
    Neslihan Şahin
    Bekir Çetinkaya
    Monatshefte für Chemie - Chemical Monthly, 2007, 138 : 205 - 209
  • [46] ASYMMETRIC TRANSFER HYDROGENATION OF AROMATIC KETONES CATALYZED BY CHIRAL RUTHENIUM(II) COMPLEXES
    HASHIGUCHI, S
    FUJII, A
    TAKEHARA, J
    IKARIYA, T
    NOYORI, R
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (28) : 7562 - 7563
  • [47] Transfer hydrogenation of ketones catalyzed by 1-alkylbenzimidazole ruthenium(II) complexes
    Ozdemir, Ismail
    Sahin, Neslihan
    Cetinkaya, Bekir
    MONATSHEFTE FUR CHEMIE, 2007, 138 (03): : 205 - 209
  • [48] Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Enantiopure Osmium(II) Pybox Complexes
    Vega, Esmeralda
    Lastra, E.
    Gamasa, M. Pilar
    INORGANIC CHEMISTRY, 2013, 52 (10) : 6193 - 6198
  • [49] Asymmetric transfer hydrogenation of aromatic ketones catalyzed by chiral ruthenium(II) complexes
    J Am Chem Soc, 28 (7562):
  • [50] Manganese catalyzed asymmetric transfer hydrogenation of ketones
    Guang-Ya Zhang
    Sun-Hong Ruan
    Yan-Yun Li
    Jing-Xing Gao
    Chinese Chemical Letters, 2021, 32 (04) : 1415 - 1418
12345