Liquid-liquid extraction of neodymium (III) and europium (III) using synergic mixture of furosemide and tribenzylamine in benzyl alcohol

被引：8
|
作者：
Abbasi, Y. A. [1 ,2 ]
Shahida, S. [3 ]
Ali, A. [4 ,5 ]
Khan, M. H. [4 ]
Khan, M. I. [6 ]
机构：
[1] Univ Azad Jammu & Kashmir, Dept Chem, Muzaffarabad, Ajk, Pakistan
[2] Govt Degree Coll Bagh, Bagh, Azad Kashmir, Pakistan
[3] Univ Poonch Rawalakot, Dept Chem, Rawalakot, Azad Kashmir, Pakistan
[4] Women Univ Azad Jammu & Kashmir Bagh, Bagh, Azad Kashmir, Pakistan
[5] Pakistan Inst Nucl Sci & Technol, Div Chem, PO Nilore, Islamabad, Pakistan
[6] Islamia Univ Bahawalpur, Dept Chem, Bahawalpur, Pakistan
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2019年 / 320卷 / 02期
关键词：
Liquid-liquid extraction; Nd(III); Eu(III); Furosemide; Tribenzylamine; Benzyl alcohol; ONLINE SPECTROPHOTOMETRIC DETERMINATION; SOLVENT-EXTRACTION; TRIVALENT LANTHANIDES; NALIDIXIC-ACID; PRECONCENTRATION; SCANDIUM; URANIUM; NITRATE; COMPLEXATION; ELEMENTS;
D O I：
10.1007/s10967-019-06467-z
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The extraction behavior of Nd(III) and Eu(III) with 0.05 mol dm(-3) furosemide in benzyl alcohol as single acidic extractant and then with equimolar (0.05 mol dm(-3)) synergic mixture of furosemide as acidic extractant and tribenzylamine as neutral donor in benzyl alcohol has been studied from aqueous solutions of pH 1 to 6. The effect of various parameters and of various cations and anions on the extraction of these metal ions was investigated. The composition of the extracted adducts was determined by slope analysis method that came out to be [(M(FS)(2))(+)(CH3COO)(-)] and [M(FS)(3) center dot 3TBA] where M=Nd(III) and Eu(III).
引用
收藏
页码：273 / 282
页数：10
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