Synthesis, Characterization, Luminescence, and Non-linear Optical Properties of Oxadiazole- and Truxene-Containing Platinum(II) Alkynyl Complexes with Donor-Acceptor Functionalities

被引:72
|
作者
Chan, Carmen Ka Man [1 ,2 ]
Tao, Chi-Hang [1 ,2 ]
Tam, Hoi-Lam [3 ,4 ]
Zhu, Nianyong [1 ,2 ]
Yam, Vivian Wing-Wah [1 ,2 ]
Cheah, Kok-Wai [3 ,4 ]
机构
[1] Univ Hong Kong, Ctr Carbon Rich Mol & Nanoscale Met Based Mat Res, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[3] Hong Kong Baptist Univ, Ctr Adv Luminescence Mat, Hong Kong, Hong Kong, Peoples R China
[4] Hong Kong Baptist Univ, Dept Phys, Hong Kong, Hong Kong, Peoples R China
关键词
EXCITATION CROSS-SECTIONS; 2-PHOTON ABSORPTION; STRUCTURAL-CHARACTERIZATION; MLCT TRANSITION; MOLECULAR FLUOROPHORES; ACETYLIDE COMPLEXES; ORGANIC-MOLECULE; BUILDING-BLOCKS; RESONANCE RAMAN; DATA STORAGE;
D O I
10.1021/ic8017979
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of luminescent platinum(II) alkynyl complexes containing 2,5-diphenyl-1,3,4-oxadiazole (oxa-2,5) and 10, 15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene (truxene) as the cores and different electron donors at the periphery has been synthesized and characterized. These complexes showed long-lived emissions in both solution and in the solid state at room temperature and have been found to exhibit two-photon absorption (2PA) and two-photon induced luminescence. Their 2PA cross-sections (sigma(2)) have also been determined.
引用
收藏
页码:2855 / 2864
页数:10
相关论文
共 44 条
  • [31] Design, synthesis, linear, and nonlinear optical properties of conjugated (porphinato)zinc(II)-based donor-acceptor chromophores featuring nitrothiophenyl and nitrooligothiophenyl electron-accepting moieties
    Zhang, TG
    Zhao, YX
    Asselberghs, I
    Persoons, A
    Clays, K
    Therien, MJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (27) : 9710 - 9720
  • [32] Synthesis, characterization, second and third order non-linear optical properties and luminescence properties of 1,10-phenanthroline-2,9-di(carboxaldehyde phenylhydrazone) and its transition metal complexes
    Prasad, G. Krishna
    Prashanth, S. S. P.
    Srivastava, S.
    Rao, G. Nageswara
    Babu, D. Rajesh
    OPEN CHEMISTRY, 2017, 15 (01): : 283 - 292
  • [33] Synthesis, characterization and non-linear optical properties of two mononuclear Cu(II) complexes of 2,6-bis(1-butylbenzimidazol-2-yl)pyridine
    Kose, Muhammet
    Ceyhan, Gokhan
    Karakas, Duran
    JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (03) : 497 - 507
  • [34] Synthesis, structural characterization, and luminescence properties of mono- and di-nuclear platinum(II) complexes containing 2-(2-pyridyl)benzimidazole
    Niknam, Fatemeh
    Hamidizadeh, Peyman
    Nabavizadeh, S. Masoud
    Hosseini, Fatemeh Niroomand
    Hoseini, S. Jafar
    Ford, Peter C.
    Abu-Omar, Mahdi M.
    INORGANICA CHIMICA ACTA, 2019, 498
  • [35] Synthesis, Spectral, Structural, Second-Order Nonlinear Optical Properties and Theoretical Studies On New Organometallic Donor-Acceptor Substituted Nickel(II) and Copper(II) Unsymmetrical Schiff-Base Complexes
    Trujillo, Alexander
    Fuentealba, Mauricio
    Carrillo, David
    Manzur, Carolina
    Ledoux-Rak, Isabelle
    Hamon, Jean-Rene
    Saillard, Jean-Yves
    INORGANIC CHEMISTRY, 2010, 49 (06) : 2750 - 2764
  • [36] Synthesis, characterization, electronic structure, and non-linear optical properties (NLO) of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes with 5-phenylazo-8-hydroxyquinoline using DFT approach
    Abdel-Latif, Samir A.
    Moustafa, H.
    APPLIED ORGANOMETALLIC CHEMISTRY, 2017, 31 (12)
  • [37] Synthesis, characterization, optical spectroscopic, electronic structure, and second-order nonlinear optical (NLO) properties of a novel class of donor-acceptor bis(salicylaldiminato)nickel(II) Schiff base NLO chromophores
    DiBella, S
    Fragala, I
    Ledoux, I
    DiazGarcia, MA
    Marks, TJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (40) : 9550 - 9557
  • [38] Syntheses, characterization and third order non-linear optical properties of the ruthenium(II) complexes containing 2-phenylimidazo[4,5-f][1,10]phenanthroline derivatives
    Chao, H
    Li, RH
    Yi, BH
    Li, H
    Feng, XL
    Cai, JW
    Zhou, JY
    Ji, LN
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (21): : 3711 - 3717
  • [39] New 1,3-dithiol-2-ylidene donor-π-acceptor chromophores with intramolecular charge-transfer properties, and related donor-π-donor molecules:: synthesis, electrochemistry, X-ray crystal structures, non-linear optical properties and theoretical calculations
    Moore, AJ
    Bryce, MR
    Batsanov, AS
    Green, A
    Howard, JAK
    McKervey, MA
    McGuigan, P
    Ledoux, I
    Orti, E
    Viruela, R
    Viruela, PM
    Tarbit, B
    JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (05) : 1173 - 1184
  • [40] Mono-, di- and tetra-nuclear ruthenium(II) complexes containing 2,2′-p-phenylenebis( imidazo[4,5-f]phenanthroline):: synthesis, characterization and third-order non-linear optical properties
    Chao, H
    Li, RH
    Jiang, CW
    Li, H
    Ji, LN
    Li, XY
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (12): : 1920 - 1926